Palladium(ii )-catalyzed enantioselective desymmetrization ring opening of oxabicyclic alkenes with alkynylanilines: efficient access to enantioenriched functionalized cyclohexenes
文献类型： 外文期刊
第一作者： Tan, Binhong
作者： Tan, Binhong;Meng, Junjie;Liu, Qianru;Chen, Shixin;Li, Zhaodong;Zhang, Yuping;Zhang, Yue;Li, Zhaodong;Xue, Mingyue
作者机构：
期刊名称：ORGANIC CHEMISTRY FRONTIERS （ 影响因子：4.7； 五年影响因子：4.5 ）
ISSN： 2052-4129
年卷期： 2025 年 12 卷 13 期
页码：
收录情况： SCI
摘要： We disclose herein a practical enantioselective desymmetrization ring-opening coupling of oxabicyclic alkenes with alkynylanilines, enabled by Pd(ii)-catalyzed aminopalladation cascade, allowing efficient access to a diverse set of indolated cyclohexenes bearing four contiguous densely functionalized carbon stereocenters in high yields with excellent diastereo- and enantioselectivities. Representative post-transformations to other valuable enantioenriched functionalized cyclohexene derivatives demonstrate the synthetic potential of this methodology.
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