Electrochemical Reductive Arylation of Nitroarenes with Arylboronic Acids

文献类型: 外文期刊

第一作者: Wang, Dan

作者: Wang, Dan;Wan, Zhaohua;Zhang, Heng;Yi, Hong;Lei, Aiwen;Wang, Dan;Alhumade, Hesham;Alhumade, Hesham;Lei, Aiwen

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关键词: diarylamine; electrochemistry; homogeneous catalysis; metal-free; reductive arylation

期刊名称:CHEMSUSCHEM ( 影响因子:8.928; 五年影响因子:8.868 )

ISSN: 1864-5631

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收录情况: SCI

摘要: The synthesis of diarylamine is extremely important in organic chemistry. Herein, a novel electrochemical reductive arylation of nitroarenes with arylboronic acids was developed. A variety of diarylamines were synthesized without the need for transition-metal catalysts. The reaction could be scaled up efficiently in a flow cell and several derivatization reactions were carried out smoothly. Cyclic voltammetry experiments and mechanism studies showed that acetonitrile, formic acid, and triethyl phosphite all played a role in promoting this reductive arylation transformation.

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