Influence of Cd on atrazine degradation and the formation of three primary metabolites in water under the combined pollution

文献类型： 外文期刊

第一作者： Xie, Dongyu

作者： Xie, Dongyu;Chen, Chuansheng;Xie, Dongyu;Li, Cui;Wang, Qinghai

作者机构：

关键词： Aquatic pollution; Atrazine; Cadmium; Combined pollution; Herbicide persistence

期刊名称：ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH （ 影响因子：4.223； 五年影响因子：4.306 ）

ISSN： 0944-1344

年卷期： 2021 年 28 卷 13 期

页码：

收录情况： SCI

摘要： To understand the influence of Cd on atrazine (ATZ) degradation in aqueous solution, the degradation of different initial levels of ATZ (0.1, 0.5, 1.0, and 2.0 mg center dot L-1) was investigated in the presence and absence of Cd2+ in a 20-day laboratory experiment. It was found that Cd2+ caused a significant decrease in ATZ degradation and increased its half-life from 17-34 days to 30-57 days (p < 0.0001). Regarding the three most common metabolites of ATZ, deethylatrazine (DEA) and deisopropylatrazine (DIA) were detected in water earlier than hydroxyatrazine (HYA). The DEA content was several times higher than the DIA and HYA contents, regardless of the presence or absence of Cd2+. In the presence of Cd2+, the DIA content was significantly lower and the HYA content was significantly higher. Furthermore, Cd2+ had a dose-dependent effect on HYA formation. Our results indicated that the coexistence of Cd2+ and ATZ resulted in greater herbicide persistence, thereby possibly increasing the risk of environmental contamination. DEA was still the predominant ATZ degradation product detected in water under the combined pollution, which was similar to the ATZ tendency.

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