Structure and Temperature Induced Crystallization of Natural Rubber with Different Milling Times

文献类型: 外文期刊

第一作者: Wang, Yueqiong

作者: Wang, Yueqiong;Li, Zechun;Liao, Shuangquan;Wang, Yueqiong;Zhao, Pengfei;Liu, Hongchao;Zhang, Fuquan;Gong, Wei;Xu, Kui;Peng, Zheng;Liao, Lusheng;Xu, Tiwen

作者机构:

期刊名称:POLYMER SCIENCE SERIES A ( 影响因子:0.968; 五年影响因子:0.958 )

ISSN: 0965-545X

年卷期: 2021 年 63 卷 3 期

页码:

收录情况: SCI

摘要: Crystallization, a characteristic property of natural rubber, has great effect on the storage and application in industrial. Based on different milling times, natural rubber samples were prepared. Moreover, structure of natural rubber with different milling times, i.e. molecular weight, group transform, cross-link density (entanglement), and rheology were analyzed by gel permeation chromatograph (GPC), Fourier transform infrared spectrum (FTIR), and rubber processing analyzer (RPA), respectively. Furthermore, temperature induced crystallization parameters were mounted on differential scanning calorimeter (DSC). The results demonstrated that temperature induced crystallization rate decreased with the increment of milling times, whereas the average molecular weight measured by GPC decreased with milling times increasing. However, the average cross-link molecular weight increased which was compatible to the temperature induced crystallization rate. It was concluded that temperature induced crystallization rate was related to the average cross-link molecular weight, but not average molecular weight.

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