Room-temperature synthesis of fluorinated covalent organic framework coupled with liquid chromatography-mass spectrometry for determination of per- and polyfluoroalkyl substances in drinking water
文献类型: 外文期刊
第一作者: Xu, Guiju
作者: Xu, Guiju;Yang, Chunlei;Zhang, Hongwei;Li, Baoyu
作者机构:
关键词: Fluorinated covalent organic framework; Solid-phase extraction; PFASs; HPLC-MS/MS; water
期刊名称:JOURNAL OF CHROMATOGRAPHY A ( 影响因子:4.0; 五年影响因子:3.6 )
ISSN: 0021-9673
年卷期: 2025 年 1739 卷
页码:
收录情况: SCI
摘要:
The routine monitoring of per- and polyfluoroalkyl substances (PFASs) in drinking water has become an important task in the field of public health. In this study, a fluorinated covalent organic framework (COF) was synthesized at room temperature using tetra-(4-aminophenyl) methane (TAM) and 2,3,5, 6-tetrafluoro-terephthalal (TFTA) as building blocks and named as TAM-TFTA-COF. The adsorption characteristics of PFASs on the TAM-TFTA-COF were investigated through adsorption model-fitting and molecular calculation. The TAM-TFTA-COF was served as the solid phase extraction (SPE) cartridge packing for the enrichment of PFASs. Combined with liquid chromatography-tandem mass spectrometry, the proposed method showed good linearity in the range of 1.25-375 ng
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