Room-temperature synthesis of fluorinated covalent organic framework coupled with liquid chromatography-mass spectrometry for determination of per- and polyfluoroalkyl substances in drinking water

文献类型: 外文期刊

第一作者: Xu, Guiju

作者: Xu, Guiju;Yang, Chunlei;Zhang, Hongwei;Li, Baoyu

作者机构:

关键词: Fluorinated covalent organic framework; Solid-phase extraction; PFASs; HPLC-MS/MS; water

期刊名称:JOURNAL OF CHROMATOGRAPHY A ( 影响因子:4.0; 五年影响因子:3.6 )

ISSN: 0021-9673

年卷期: 2025 年 1739 卷

页码:

收录情况: SCI

摘要: The routine monitoring of per- and polyfluoroalkyl substances (PFASs) in drinking water has become an important task in the field of public health. In this study, a fluorinated covalent organic framework (COF) was synthesized at room temperature using tetra-(4-aminophenyl) methane (TAM) and 2,3,5, 6-tetrafluoro-terephthalal (TFTA) as building blocks and named as TAM-TFTA-COF. The adsorption characteristics of PFASs on the TAM-TFTA-COF were investigated through adsorption model-fitting and molecular calculation. The TAM-TFTA-COF was served as the solid phase extraction (SPE) cartridge packing for the enrichment of PFASs. Combined with liquid chromatography-tandem mass spectrometry, the proposed method showed good linearity in the range of 1.25-375 ngL-1, low limits of detection (0.03-0.24 ngL-1), and excellent intraday and interday precisions with RSD <10.3 %. Furthermore, this analytical method can be utilized for the determination of PFASs in tap water, spring water, and lake water with satisfactory accuracy.

分类号:

  • 相关文献
作者其他论文 更多>>