On-Site Supramolecular Adhesion to Wet and Soft Surfaces via Solvent Exchange
文献类型: 外文期刊
第一作者: Cai, Changyong
作者: Cai, Changyong;Wu, Shuanggen;Dong, Shengyi;Li, Fenfang;Tan, Zhijian
作者机构:
关键词: Supramolecular polymers; Supramolecular adhesives; Wet and soft surfaces; Solvent exchange; On-site adhesion
期刊名称:ACS APPLIED MATERIALS & INTERFACES ( 影响因子:9.229; 五年影响因子:9.57 )
ISSN: 1944-8244
年卷期: 2021 年 13 卷 44 期
页码:
收录情况: SCI
摘要: A series of poly(thioctic acid-catechol)s was prepared by supramolecular copolymerization of two low-molecular-weight monomers, thioctic acid (TA) and catechol (CA). The addition of a small amount of CA molecules significantly improved the adhesion ability of poly(TA) and transformed it into an applicable supramolecular polymer adhesive material. The robust adhesion of poly(TA-CA)s to soft surfaces was achieved by employing a hot-melt method. However, the supramolecular adhesion via the hot-melt method failed to perform in the presence of water. On-site supramolecular adhesion to wet and soft substrates was successfully realized through the solvent exchange behavior between water and the poly(TA-CA)s ethanol solution. Compared to the hot-melt method, the solvent exchange method displays various fascinating advantages and is suitable for adhesion conditions normally under the presence of water.
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