Determination of Aflatoxin B-1 and B-2 in Vegetable Oils Using Fe3O4/rGO Magnetic Solid Phase Extraction Coupled with High-Performance Liquid Chromatography Fluorescence with Post-Column Photochemical Derivatization

文献类型： 外文期刊

第一作者： Yu, Li

作者： Yu, Li;Ma, Fei;Zhang, Liangxiao;Li, Peiwu;Yu, Li;Ma, Fei;Zhang, Liangxiao;Li, Peiwu;Yu, Li;Ma, Fei;Li, Peiwu;Ma, Fei;Zhang, Liangxiao;Li, Peiwu;Zhang, Liangxiao;Li, Peiwu

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关键词： aflatoxin; magnetic solid phase extraction; graphene; high-performance liquid chromatography fluorescence; vegetable oil

期刊名称：TOXINS （ 影响因子：4.546； 五年影响因子：4.8 ）

ISSN：

年卷期： 2019 年 11 卷 11 期

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收录情况： SCI

摘要： In this study, magnetic graphene nanocomposite Fe3O4/rGO was synthesized by facile one-pot solvothermal method. The nanocomposite was successfully used as magnetic solid phase extraction (MSPE) adsorbents for the determination of aflatoxins in edible vegetable oils through the pi-pi stacking interactions. MSPE parameters including the amount of adsorbents, extraction and desorption time, washing conditions, and the type and volume of desorption solvent were optimized. Under optimal conditions, good linear relationships were achieved. Limits of detection of this method were as low as 0.02 mu g/kg and 0.01 mu g/kg for aflatoxin B-1 and B-2, respectively. Finally, the magnetic graphene nanocomposite was successfully applied to aflatoxin analysis in vegetable oils. The results indicated that the recoveries of the B-group aflatoxins ranged from 80.4% to 106.0%, whereas the relative standard deviations (RSDs) were less than 8.1%. Owing to the simplicity, rapidity and efficiency, Fe3O4/rGO magnetic solid phase extraction coupled with high-performance liquid chromatography fluorescence with post-column photochemical derivatization (Fe3O4/rGO MSPE-HPLC-PCD-FLD) is a promising analytical method for routine and accurate determination of aflatoxins in lipid matrices.

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