Enantioselective intermolecular iodoacetalization of enol ethers catalyzed by chiral Co(III)-complex-templated Bronsted acids

文献类型: 外文期刊

第一作者: Li, Na

作者: Li, Na;Yu, Hao;Wang, Rui;Wu, Wen-Qiang;Sun, Ting-Ting;Yao, Chuan-Zhi;Yu, Jie;Shen, Jia;Liu, Kun;Zhang, Zheng-Zhu;Yu, Jie

作者机构:

关键词: Chiral Co(III) complexes; Bronsted acid; Intermolecular; Iodoacetalization

期刊名称:TETRAHEDRON LETTERS ( 影响因子:2.415; 五年影响因子:2.036 )

ISSN: 0040-4039

年卷期: 2018 年 59 卷 40 期

页码:

收录情况: SCI

摘要: The chiral Co(III)-complex-templated Brensted acids were used as efficient bifunctional phase-transfer catalysts for the asymmetric intermolecular iodoacetalization of enol ethers, such as 3,4-dihydro-2H-pyran, 2,3-dihydrofuran, ethyl vinyl ether with alcohols and NIS, furnishing the 3-iodoacetals in high yield with up to 83:17 er. (C) 2018 Elsevier Ltd. All rights reserved.

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