Chemical aging of hydrochar improves the Cd2+ adsorption capacity from aqueous solution
文献类型: 外文期刊
第一作者: Li, Detian
作者: Li, Detian;Cui, Hongbiao;Li, Detian;Xue, Lihong;He, Huayong;Chu, Qingnan;Feng, Yanfang;Yang, Linzhang;Li, Detian;Xue, Lihong;He, Huayong;Chu, Qingnan;Feng, Yanfang;Yang, Linzhang;Cheng, Yueqin;Xue, Lihong;Hua, Yun;Feng, Yanfang;Xue, Lihong;He, Huayong;Feng, Yanfang;Wang, Bingyu;Li, Detian;Cui, Hongbiao;Chu, Qingnan
作者机构:
关键词: Hydrochar; Chemical aging; Cadmium; Surface functional groups; Ion exchange
期刊名称:ENVIRONMENTAL POLLUTION ( 影响因子:8.071; 五年影响因子:8.35 )
ISSN: 0269-7491
年卷期: 2021 年 287 卷
页码:
收录情况: SCI
摘要: Hydrochar (HC) serves as a promising adsorbent to remove the cadmium from aqueous solution due to porous structure. The chemical aging method is an efficient and easy-operated approach to improve the adsorption capacity of HC. In this study, four chemical aging hydrochars (CAHCs) were obtained by using nitric acid (HNO3) with mass fractions of 5% (N5-HC), 10% (N10-HC), and 15% (N15-HC) to age the pristine HC (N0-HC) and remove the Cd2+ from the aqueous solution. The results displayed that the N15-HC adsorption capacity was 19.99 mg g(-1) (initial Cd2+ concentration was 50 mg L-1), which increased by 7.4 folds compared to N0-HC. After chemical aging, the specific surface area and oxygen-containing functional groups of CAHCs were increased, which contributed to combination with Cd2+ by physical adsorption and surface complexation. Moreover, ion exchange also occurred during the adsorption process of Cd2+. These findings have important implications for wastewater treatment to transform the forestry waste into a valuable adsorbent for Cd2+ removal from water.
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