High-performance supercapacitors based on coarse nanofiber bundle and ordered network hydrogels

文献类型： 外文期刊

第一作者： Zhang, Dong-Yang

作者： Zhang, Dong-Yang;Chen, Tao

作者机构：

关键词： Coarse nanofiber bundle and ordered network; Silk nanofiber; Cartilage structure; Hydrogel supercapacitors

期刊名称：INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES （ 影响因子：8.5； 五年影响因子：8.7 ）

ISSN： 0141-8130

年卷期： 2025 年 292 卷

页码：

收录情况： SCI

摘要： Most of the developed flexible hydrogel supercapacitors struggle to maintain their electrochemical stability and structural integrity under tensile strain. Therefore, developing a flexible supercapacitor with excellent mechanical properties and stable electrochemical performance under different strains remains a challenge. Based on the previous cartilage-like structure, we designed a new coarse nanofiber bundle and ordered network. A coarse nanofiber bundle and ordered network skeleton was constructed by directional freezing and filled with polyvinyl alcohol (PVA) to serve as a soft matrix to prepare PVA-SNF-CNTs-PPy-3 hydrogel electrode, which has high tensile strength (6.22 MPa) and fatigue threshold (8759.8 J/m(2)). In addition, the loading of carbon nanotubes and polypyrrole onto the SNF-ordered network enabled the conductive material to form an ordered conductive energy storage network along the skeleton, providing an area-specific capacitance of up to 23.96 F/cm(2). The coarse nanofiber bundle and ordered network provided supercapacitors with the least capacitance consumption under 150 % deformation, and the capacitance retention was >98.2 %. After repeated stretching (3000 times), the capacitance remained >91.45 %. This study provides new ideas for the development of flexible supercapacitors with high capacitance and high mechanical reliability.

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