Influence of Soil Properties on the Enantioselective Dissipation of the Herbicide Lactofen in Soils

文献类型： 外文期刊

第一作者： Diao, Jinling

作者： Diao, Jinling;Lv, Chunguang;Dang, Ziheng;Zhu, Wentao;Zhou, Zhiqiang;Wang, Xinquan

作者机构：

关键词： Enantioselective dissipation;enantiomer;lactofen;soil pH;soil texture

期刊名称：JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY （ 影响因子：5.279； 五年影响因子：5.269 ）

ISSN：

年卷期：

页码：

收录情况： SCI

摘要： A scheme was developed to elucidate the dissipation behaviors of the two enantiomers of the herbicide lactofen in soils using a normal-phase high-performance liquid chromatograph (HPLC) with UV detector and a column with a cellulose-tri-(3,5-dimethylphenylcarbamate)-based chiral stationary phase (CDMPC-CSP). Eight soils with a wide range of soil properties were studied. Racemic and the enantiopure (S)-(+)- and (R)-(-)-lactofen were incubated under aerobic and anaerobic conditions. The data from sterilized controls indicated that the dissipation of lactofen was biological. The dissipation was shown to be enantioselective with (S)-(+)-enantiomer being degraded faster than the (R)-(-)-enantiomer, resulting in residues enriched with (R)-(-)-lactofen when the racemic compound was incubated. Lactofen was configurationally stable in soil, showing no interconversion of (S)-(+)- to (R)-(-)- enantiomer and vice versa. Significant correlations of the enantioselectivity, expressed as ES = (k_(S)) - k_(R))/(k_(S) + k_(R)) of lactofen with soil pH were observed under aerobic and anaerobic conditions. In addition, we found that the enantioselectivity correlated with the soil texture rather than the organic carbon.

分类号： R15

  • 相关文献

[1]Detoxification of diphenyl ether herbicide lactofen by Bacillus sp Za and enantioselective characteristics of an esterase gene lacE. Zhang, Jing,Lu, Luyao,Chen, Feng,Chen, Lingling,Huang, Xing,Zhang, Jing,Yin, Jingang. 2018

[2]Enantioselective Residue Dissipation of Hexaconazole in Cucumber (Cucumis sativus L.), Head Cabbage (Brassica oleracea L. var. caulorapa DC.), and Soils. Wang, Xinquan,Zhang, Hu,Xu, Hao,Wang, Xiangyun,Wu, Changxing,Li, Zhen,Wang, Qiang,Yang, Hongda. 2012

[3]The application of chiral ultra-high-performance liquid chromatography tandem mass spectrometry to the separation of the zoxamide enantiomers and the study of enantioselective degradation process in agricultural plants. Dong, Fengshou,Chen, Zenglong,Xu, Jun,Liu, Xingang,Wu, Xiaohu,Zheng, Yongquan.

[4]Biochemical characterization of an enantioselective esterase from Brevundimonas sp LY-2. Zhang, Jing,Zhao, Mengjun,Yu, Die,Zhang, Hao,Huang, Xing,Zhang, Jing,Yin, Jingang. 2017

[5]Enantioselective accumulation of chiral polychlorinated biphenyls in lotus plant (Nelumbonucifera spp.). Dai, Shouhui,Qiu, Jing,Wang, Min,Chai, Tingting,Fan, Li,Yang, Shuming,Dai, Shouhui,Qiu, Jing,Wang, Min,Chai, Tingting,Fan, Li,Yang, Shuming,Wong, Charles S.,Dai, Shouhui. 2014

[6]Comparison of Enantioseparations of 19 Chiral Polychlorinated Biphenyls by 5 Different Polysaccharides Chiral Columns. Xu Na-Na,Mu Peng-Qian,Jia Qi,Chai Ting-Ting,Yin Zhi-Qiang,Shu-Ming, Yang,Jing, Qiu,Chai Ting-Ting. 2015

[7]Determination of Polychlorinated Biphenyl Enantiomers in Lotus Root and Sediment by Chiral Gas Chromatography-Mass Spectrometry. Dai Shou-Hui,Zhao Hua-Lin,Wang Min,Chai Ting-Ting,Yang Shu-Ming,Qiu Jing,Dai Shou-Hui,Zhao Hua-Lin,Wang Min,Chai Ting-Ting,Yang Shu-Ming,Qiu Jing,Wong, Charles S.. 2012

[8]Resolution of racemic gamma-lactone flavors on Chiralpak AD by packed column supercritical fluid chromatography. Xie, Jianchun,Han, Huilan,Sun, Baoguo,Cheng, Jie,Yanik, Gary W.. 2011

[9]Enantiomeric analysis of linalool in teas using headspace solid-phase microextraction with chiral gas chromatography. Yang, Ting,Zhu, Yin,Shao, Chen-Yang,Zhang, Yue,Shi, Jiang,Lv, Hai-Peng,Lin, Zhi,Yang, Ting,Shao, Chen-Yang,Shi, Jiang.

[10]Distribution Characteristics of Soil Cadmium in Different Textured Paddy Soil Profiles and Its Relevance with Cadmium Uptake by Crops. Wang Zheng-yin,Qin Yu-sheng,Zhan Shao-jun,Yu Hua,Tu Shi-hua. 2013

[11]The effect of plant hedgerows on the spatial distribution of soil erosion and soil fertility on sloping farmland in the purple-soil area of China. Tu, Shihua,Huang, Jingjing,Chen, Yibing,Lin, Chaowen.

[12]Pedotransfer Functions for Estimating Soil Bulk Density: A Case Study in the Three-River Headwater Region of Qinghai Province, China. Yi Xiangsheng,Yi Xiangsheng,Li Guosheng,Yin Yanyu. 2016

[13]Ammonia toxicity in aerobic rice: use of soil properties to predict ammonia volatilization following urea application and the adverse effects on germination. Haden, V. R.,Hobbs, P.,Duxbury, J. M.,Xiang, J.,Peng, S.,Ketterings, Q. M..

[14]Climate, soil texture, and soil types affect the contributions of fine-fraction-stabilized carbon to total soil organic carbon in different land uses across China. Cai, Andong,Zhang, Wenju,Xu, Minggang,Feng, Wenting.

[15]Quantitative effects of wind erosion on the soil texture and soil nutrients under different vegetation coverage in a semiarid steppe of northern China. Yan, Yuchun,Xin, Xiaoping,Wang, Xu,Yang, Guixia,Yan, Ruirui,Chen, Baorui,Yan, Yuchun,Xin, Xiaoping,Wang, Xu,Yang, Guixia,Yan, Ruirui,Chen, Baorui,Yan, Yuchun,Xin, Xiaoping,Wang, Xu,Yang, Guixia,Yan, Ruirui,Chen, Baorui,Xu, Xingliang.

[16]How rain-formed soil crust affects wind erosion in a semi-arid steppe in northern China. Yan, Yuchun,Xin, Xiaoping,Wang, Xu,Yang, Guixia,Yan, Yuchun,Xin, Xiaoping,Wang, Xu,Yang, Guixia,Yan, Yuchun,Xin, Xiaoping,Wang, Xu,Yang, Guixia,Wu, Lianhai.

[17]Water and salt movement in different soil textures under various negative irrigating pressures. Wang Jia-jia,Huang Yuan-fang,Wang Jia-jia,Long Huai-yu. 2016

[18]Effects of water stress on growth and mineral composition of 'Gala' apple fruit. Yao, SG,Neilsen, GH,Neilsen, D.

[19]Analysis of the inhibitory effects of chloropicrin fumigation on nitrification in various soil types. Wang, Qiuxia,Li, Yuan,Ouyang, Canbin,Guo, Meixia,Cao, Aocheng.

[20]Salinity of animal manure and potential risk of secondary soil salinization through successive manure application. Guo-Liang, Li,Shi-Hua, Tu,Gavin, Sulewski,Zhao-Huan, He. 2007

作者其他论文 更多>>

微信小程序