Sustainable Photo- and Electrochemical Transformation of White Phosphorous (P4) into P1 Organo-Compounds

文献类型： 外文期刊

第一作者： Liu, Yan

作者： Liu, Yan;Liu, Yan;Chen, Xiaolan;Yu, Bing;Liu, Yan

作者机构：

关键词： electrochemistry; organophosphorus compounds; photochemistry; sustainability; white phosphorus

期刊名称：CHEMISTRY-A EUROPEAN JOURNAL （ 影响因子：4.3； 五年影响因子：4.1 ）

ISSN： 0947-6539

年卷期： 2023 年

页码：

收录情况： SCI

摘要： Elemental white phosphorous (P-4) is a crucial feedstock for the entire phosphorus-derived chemical industry, serving as a common precursor for the ultimate preparation of high-grade monophosphorus (P-1) fine chemicals. However, the corresponding manufacturing processes generally suffer from a deep reliance on hazardous reagents, inputs of immense energy, emissions of toxic pollutants, and the generation of substantial waste, which have negative impacts on the environment. In this context, sustainability and safety concerns provide a consistent impetus for the urgent overall improvement of phosphorus cycles. In this Concept, we present an overview of the most recent growth in photo- and electrochemical synthesis of P-1 organo-compounds from P-4, with special emphasis on sustainable features. The key aspects of innovations regarding activation mode and mechanism have been comprehensively analyzed. A preliminary look at the possible future direction of development is also provided.

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