Unraveling the Enantiomeric Distribution of Glycosidically Bound Linalool in Teas (Camellia sinensis) and Their Acidolysis Characteristics and Pyrolysis Mechanism
文献类型： 外文期刊
第一作者： Yan, Han
作者： Yan, Han;Lin, Zhiyuan;Li, Weixuan;Gao, Jianjian;Li, Pengliang;Chen, Qincao;Lv, Haipeng;Zhang, Yue;Dai, Weidong;Lin, Zhi;Zhu, Yin;Yan, Han;Lin, Zhiyuan
作者机构：
关键词： enantiomeric distribution; linalyl-beta-primeveroside; linalool; tea; acidolysis characteristics; pyrolysis mechanism
期刊名称：JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY （ 影响因子：6.1； 五年影响因子：6.3 ）
ISSN： 0021-8561
年卷期： 2024 年 72 卷 16 期
页码：
收录情况： SCI
摘要： Glycosidically bound linalool plays important roles in the formation of excellent tea flavor, while their enantiomeric distribution in teas and the actual transformations with free linalool are still unclear. In this study, a novel chiral ultrahigh performance liquid chromatography-mass spectrometry/mass spectrometry approach to directly analyze linalyl-beta-primeveroside and linalyl-beta-d-glucopyranoside enantiomers in teas was established and then applied in 30 tea samples. A close transformation relationship existed between the two states of linalool for their consistent dominant configurations (most S-form) and corresponding distribution trend in most teas (r up to 0.81). The acidolysis characterization indicated that free linalool might be slowly released from linalyl-beta-primeveroside with stable enantiomeric ratios during long-term withering of white tea in a weakly acidic environment, along with other isomerized products, e.g., geraniol, nerol, alpha-terpineol, etc. Furthermore, a novel online thermal desorption-gas chromatography-mass spectrometry approach was established to simulate the pyrolysis releasing of linalyl-beta-primeveroside during tea processing. Interestingly, free linalool was not the selected pyrolysis product of linalyl-beta-primeveroside but rather trans/cis-2,6-dimethyl-2,6-octadiene during the high-fire roasting or baking step of oolong and green teas. The identification of above high-fire chemical marks presented great potential to scientifically evaluate the proper thermal conditions in the practical production of tea.
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