Polychlorinated Dibenzo-p-dioxin And Dibenzofurans (pcdd/fs), Polybrominated Diphenyl Ethers (pbdes), And Polychlorinated Biphenyls (pcbs) Monitored By Tree Bark In An E-waste Recycling Area
文献类型: 外文期刊
第一作者: Wen, Sheng
作者: Wen, Sheng;Yang, F.;Zhang, X. L.;Hui, Y.;Xu, Ying;Wen, Sheng;Li, J. G.;Wu, Y. N.;Zhao, Y. F.;Gong, Yan
作者机构:
关键词: tree bark;e-waste;pcdd/fs;pbdes;PCBS;profile
期刊名称:CHEMOSPHERE ( 影响因子:7.086; 五年影响因子:6.956 )
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收录情况: SCI
摘要: To investigate the environmental levels and profiles of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polybrominated diphenyl ethers (PBDEs), and polychlorinated biphenyls (PCBs), tree bark samples (n = 22) were collected from Luqiao, an E-waste recycling area, in east China in July 11-13,2006. The average concentrations of PCDD/Fs, PBDEs, and PCBs determined by isotope dilution-high resolution gas chromatography (HRGC) coupled with high resolution mass spectrometer (HRMS) were 0.1 ±0.0, 1.4 ±0.2, and 6.5±0.8 μg g~(-1) lipid weight, respectively. PCDD/F-toxic equivalent (TEQ, WHO-1998), PCB-TEQs, and total dioxin-like TEQs were 1.3 ± 0.1, 0.5 ± 0.0, and 1.8 ± 0.2 ng g~(-1) lipid weight, respectively. The profiles of these pollutants in the tree bark were also discussed. Tetra-CDFs, deca-BDE and tri-CBs were the main homologues and accounted for 47% of total PCDD/Fs, 79.3% of total PBDEs, and 33.2% of total PCBs, respectively; As for TEQs, 2,3,4,7,8-PeCDF and PCB126 were the main contributors and accounted for 36% of the total PCDD/F-TEQs and 81.2% of the total PCB-TEQs, respectively. High accumulation of PCDD/Fs, PBDEs, and PCBs detected in the tree bark indicated heavy contaminations of these pollutants in Luqiao area.
分类号: X51
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