Residue analysis of four diacylhydrazine insecticides in fruits and vegetables by Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method using ultra-performance liquid chromatography coupled to tandem mass spectrometry

文献类型： 外文期刊

第一作者： Liu, Xingang

作者： Liu, Xingang;Xu, Jun;Dong, Fengshou;Li, Yuanbo;Zheng, Yongquan;Song, Wenchen

作者机构：

关键词： Diacylhydrazine insecticide;Fruits;Residue analysis;Ultra-performance liquid chromatography-mass spectrometry;Vegetables

期刊名称：ANALYTICAL AND BIOANALYTICAL CHEMISTRY （ 影响因子：4.142； 五年影响因子：3.863 ）

ISSN：

年卷期：

页码：

收录情况： SCI

摘要： The new analytical method using Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) procedure for simultaneous determination of diacylhydrazine insecticide residues in fruits and vegetables was developed using ultra-performance liquid chromatography coupled with tandem mass spectrometry (UPLC-MS/MS). The four insecticides (tebufenozide, methoxfenozide, chromafenozide, and halofenozide) were extracted from six fruit and vegetable matrices using acetonitrile and subsequently cleaned up using primary secondary amine (PSA) or octadecylsilane (C18) as sorbent prior to UPLC-MS/MS analysis. The determination of the target compounds was achieved in less than 3.0 min using an electrospray ionization source in positive mode (ESI+) for tebufenozide, methoxfenozide, and halofenozide and in negative mode (ESI-) for chromafenozide. The limits of detection were below 0.6 μg kg-1, while the limit of quantification did not exceed 2 μg kg~(-1) in different matrices. The QuEChERS procedure by using two sorbents (PSA and C18) and the matrix-matched standards gave satisfactory recoveries and relative standard deviation (RSD) values in different matrices at four spiked levels (0.01, 0.05, 0.1, and 1 mg kg~(-1)). The overall average recoveries for this method in apple, grape, cucumber, tomato, cabbage, and spinach at four levels ranged from 74.2% to 112.5% with RSDs in the range of 1.4-13.8% (n∈=∈5) for all analytes. This study provides a theoretical basis for China to draw up maximum residue limits and analytical method for diacylhydrazine insecticide in vegetables and fruits.

分类号： O65

  • 相关文献

[1]Rapid residue analysis of four triazolopyrimidine herbicides in soil, water, and wheat by ultra-performance liquid chromatography coupled to tandem mass spectrometry. Liu, Xingang,Xu, Jun,Li, Yuanbo,Dong, Fengshou,Li, Jing,Zheng, Yongquan,Song, Wenchen.

[2]Determination of cyflumetofen residue in water, soil, and fruits by modified quick, easy, cheap, effective, rugged, and safe method coupled to gas chromatography/tandem mass spectrometry. Liu, Xingang,Dong, Fengshou,Xu, Jun,Zheng, Yongquan,Li, Minmin,Zheng, Yongquan,Qin, Dongmei.

[3]Principles, developments and applications of computer vision for external quality inspection of fruits and vegetables: A review. Zhang, Baohua,Huang, Wenqian,Li, Jiangbo,Zhao, Chunjiang,Fan, Shuxiang,Wu, Jitao,Zhang, Baohua,Zhao, Chunjiang,Liu, Chengliang. 2014

[4]Determination of imidacloprid,carbendazim and thiabendazole residues in vegetables and fruits by HPLC. Lin, Ling,Peng, Zheng,Yang, Chunliang,Wang, Mingyue,Zha, Yubing,Liu, Lili,Zeng, Shaodong. 2013

[5]Determination of organochlorine pesticides in propolis by gas chromatography-electron capture detection using double column series solid-phase extraction. Chen, Fang,Chen, Lanzhen,Zhou, Jinhui,Xue, Xiaofeng,Zhao, Jing,Wang, Qiang.

[6]Monitoring, exposure and risk assessment of sulfur dioxide residues in fresh or dried fruits and vegetables in China. Lou, Tiantian,Huang, Weisu,Wu, Xiaodan,Wang, Mengmeng,Lu, Baiyi,Hu, Yinzhou,Huang, Weisu,Zhou, Liying,Zheng, Lufei.

[7]Determination of ametoctradin residue in fruits and vegetables by modified quick, easy, cheap, effective, rugged, and safe method using ultra-performance liquid chromatography/tandem mass spectrometry. Liu, Xingang,Dong, Fengshou,Xu, Jun,Li, Shasha,Xu, Hanqing,Zheng, Yongquan. 2015

[8]Simultaneous determination of pyrimethanil, cyprodinil, mepanipyrim and its metabolite in fresh and home-processed fruit and vegetables by a QuEChERS method coupled with UPLC-MS/MS. Liu, Xingang,Dong, Fengshou,Xu, Jun,Li, Yuanbo,Tian, Yingying,Zhang, Ying,Han, Yongtao,Zheng, Yongquan,Qin, Dongmei. 2013

[9]A novel approach for simultaneous determination of E/Z-fluoxastrobins in vegetables and fruits by UHPLC-DAD. Sun, Qiang,Wang, Weimin,Li, Yubo,Wen, Guangyue,Tang, Hongxia,Song, Weiguo,Dong, Maofeng,Sun, Qiang,Tang, Hongxia.

[10]Simultaneous determination of organophosphorus pesticides in fruits and vegetables using atmospheric pressure gas chromatography quadrupole-time-of-flight mass spectrometry. Dong, Fengshou,Xu, Jun,Liu, Xingang,Wu, Xiaohu,Chen, Zenglong,Pan, Xinglu,Zheng, Yongquan,Dong, Fengshou,Gan, Jay.

[11]Chromatographic methods for the determination of pyrethrin and pyrethroid pesticide residues in crops, foods and environmental samples. Chen, ZM,Wang, YH. 1996

[12]Multiresidue determination of benzoylurea insecticides in vegetable matrices. He Hongmei,Wu Liqin,Zhang Hu,Zhu Jiahong,Xie Lei. 2006

[13]Residue analysis and risk assessment of tebuconazole in jujube (Ziziphus jujuba Mill). You, Xiangwei,Li, Yiqiang,Wang, Xiuguo,Xu, Jinli,Zheng, Xiao,Sui, Chengcheng.

[14]Multiplug filtration cleanup method with multi-walled carbon nanotubes for the analysis of malachite green, diethylstilbestrol residues, and their metabolites in aquatic products by liquid chromatography-tandem mass spectrometry. Qin, Yuhong,Zhang, Jingru,Li, Yanjie,Han, Yongtao,Zou, Nan,Pan, Canping,Jiang, Yanbin,Shan, Jihao.

[15]Application of SPME Based on a stainless steel wire for the determination of pyrethroid insecticide residues in water and soil. Jia, Chunhong,Zhu, Xiaodan,Zhao, Ercheng,Yu, Pingzhong,He, Min,Chen, Li.

[16]Residue Determination of cis-Epoxiconazole Enantiomers in Fruit and Tea by Ultra Performance Convergence Chromatography Combined with Quadrupole Time-of-Flight Mass Spectrometry. Zhao Yue-Chen,Cui Xin-Yi,Zhang Xin-Zhong,Luo Feng-Jian,Zhou Li,Chen Zong-Mao. 2016

[17]Validated hydrophilic interaction LC-MS/MS method for determination of 2-pyrrolidinone residue: Applied to a depletion study of 2-pyrrolidinone in swine liver. Liu, Yanhong,Chen, Ximing,Ji, Yanhong,Chen, Jiangtao,Wang, Guangxiang,Shang, Youjun,Liu, Xiangtao,Pan, Jack.

[18]Distribution and elimination of Norfloxacin in Fenneropenaeus chinensis larvae. Sun Ming,Sun Ming,Li Jian,Zhao Fazhen,Li Jitao,Chang Zhiqiang. 2013

[19]Extraction of organophosphorus pesticides in water and juice using ultrasound-assisted emulsification-mixroextraction. Jia, Chunhong,Zhu, Xiaodan,Chen, Li,He, Min,Yu, Pingzhong,Zhao, Ercheng.

[20]Extraction of pesticides in water samples using vortex-assisted liquid-liquid microextraction. Jia, Chunhong,Zhu, Xiaodan,Zhao, Ercheng,He, Min,Chen, Li,Yu, Pingzhong,Jia, Chunhong,Zhu, Xiaodan,Wang, Jihua,Zhao, Ercheng,He, Min,Chen, Li,Yu, Pingzhong.

作者其他论文 更多>>

微信小程序