Enantioselective degradation of tebuconazole in cabbage, cucumber, and soils
文献类型: 外文期刊
第一作者: Wang, Xinquan
作者: Wang, Xinquan;Zhang, Hu;Wu, Changxing;Wang, Xiangyun;Xu, Hao;Wang, Xiaofu;Li, Zhen;Wang, Xuesong
作者机构:
关键词: Cabbage;Cucumber;Degradation;Enantioselective;Soil;Tebuconazole
期刊名称:CHIRALITY ( 影响因子:2.437; 五年影响因子:2.204 )
ISSN:
年卷期:
页码:
收录情况: SCI
摘要: The enantioselective degradation of tebuconazole has been investigated to elucidate the behaviors in agricultural soils, cabbage, and cucumber fruit. Rac-tebuconazole was fortified into three types of agricultural soils and sprayed foliage of cabbage and cucumber, respectively. The degradation kinetics, enantiomer fraction and enantiomeric selectivity were determined by reverse-phase high-performance liquid chromatography (HPLC) and liquid chromatography- mass spectrometry/mass spectrometry (LC-MS/MS) on a Lux amylose-2 chiral column. The process of the degradation of tebuconazole enantiomers followed first-order kinetic in the test soils and vegetables. It has been shown that the degradation of tebuconazole was enantioselective. The results indicated that the (+)-S-tebuconazole showed a faster degradation in cabbage, while the (-)-R-tebuconazole dissipated faster than (+)-S-form in cucumber fruit and the test soils.
分类号: O641
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