A quick, easy, cheap, effective, rugged, and safe method for the simultaneous detection of four triazolone herbicides in cereals combined with ultrahigh performance liquid chromatography with tandem mass spectrometry

文献类型： 外文期刊

第一作者： Tao, Yan

作者： Tao, Yan;Xu, Jun;Liu, Xingang;Cheng, Youpu;Liu, Na;Chen, Zenglong;Dong, Fengshou;Zheng, Yonguan

作者机构：

关键词： Cereals;Herbicides;Residues;Triazolone;Ultrahigh performance liquid chromatography

期刊名称：JOURNAL OF SEPARATION SCIENCE （ 影响因子：3.645； 五年影响因子：2.943 ）

ISSN：

年卷期：

页码：

收录情况： SCI

摘要： This paper describes a novel, rapid, and sensitive analytical method for monitoring four triazolone herbicides in cereals (wheat, rice, corn, and soybean), using a quick, easy, cheap, effective, rugged, and safe sample extraction procedure followed by ultrahigh performance liquid chromatography coupled with tandem mass spectrometry. The four triazolone herbicides (amicarbazone, carfentrazone-ethyl, sulfentrazone, and thiencarbazone-methyl) were extracted using acidified acetonitrile (containing 1% v/v formic acid) and subsequently purified with octadecylsilane (C_(18)) prior to sample analysis. Ultrahigh performance liquid chromatography coupled with tandem mass spectrometry was operated in positive and negative ionization switching mode. Amicarbazone and carfentrazone-ethyl were detected in the positive mode (ESI+), while sulfentrazone and thiencarbazone-methyl were detected in the negative mode (ESI-). All compounds were successfully separated in less than 3.0 min. Further optimization achieved desired recoveries ranging from 74.5 to 102.1% for all analytes with relative standard deviation values ≤17.2% in all tested matrices at three levels (10, 100, and 500 μg/kg). The limits of detection for all compounds were ≤2.3 μg/kg, and the limits of quantitation did not exceed 7.1 μg/kg. The developed method showed excellent linearity (R~2 ≥ 0.994) and was proven to be highly efficient and reliable for the routine monitoring of triazolone herbicides in cereals.

分类号： O6

  • 相关文献

[1]On-farm conservation of 12 cereal crops among 15 ethnic groups in Yunnan (PR China). Xu, Furong,A, Xinxiang,Zhang, Feifei,Zhang, Enlai,Tang, Cuifeng,Dong, Chao,Yang, Yayun,Dai, Luyuan,Xu, Furong,A, Xinxiang,Zhang, Feifei,Zhang, Enlai,Tang, Cuifeng,Dong, Chao,Yang, Yayun,Dai, Luyuan,Xu, Furong,A, Xinxiang,Zhang, Feifei,Zhang, Enlai,Tang, Cuifeng,Dong, Chao,Yang, Yayun,Dai, Luyuan,Xu, Furong,A, Xinxiang,Zhang, Feifei,Zhang, Enlai,Tang, Cuifeng,Dong, Chao,Yang, Yayun,Dai, Luyuan,Liu, Xu.

[2]Rice ragged stunt oryzavirus: role of the viral spike protein in transmission by the insect vector. Zhou, GY,Lu, XB,Lu, HJ,Lei, JL,Chen, SX,Gong, ZX.

[3]Analysis of four sulfonylurea herbicides in cereals using modified Quick, Easy, Cheap, Effective, Rugged, and Safe sample preparation method coupled with liquid chromatography-tandem mass spectrometry. Ni, Yanxia,Yang, Huan,Zhang, Hantong,He, Qiao,Huang, Siqi,Qin, Meiling,Chai, Shuangshuang,Gao, Huanhuan,Ma, Youning. 2018

[4]Detoxification of gramine by the cereal aphid Sitobion avenae. Cai, Qing-Nian,Han, Ying,Hu, Yuan,Zhao, Xin,Cao, Ya-Zhong.

[5]Research of Heavy Metals Determination in Cereals by Inductively Coupled Plasma Mass Spectrometry. Wang Bu-jun. 2012

[6]QuEChERS Purification Combined with Ultrahigh-Performance Liquid Chromatography Tandem Mass Spectrometry for Simultaneous Quantification of 25 Mycotoxins in Cereals. Sun, Juan,Li, Weixi,Zhang, Yan,Hu, Xuexu,Wu, Li,Wang, Bujun,Sun, Juan,Li, Weixi,Zhang, Yan,Hu, Xuexu,Wu, Li,Wang, Bujun. 2016

[7]Combination of dispersive solid-phase extraction and salting-out homogeneous liquid-liquid extraction for the determination of organophosphorus pesticides in cereal grains. Jia, Chunhong,Zhu, Xiaodan,Zhao, Ercheng,He, Min,Chen, Li,Yu, Pingzhong,Jia, Chunhong,Zhu, Xiaodan,Wang, Jihua,Zhao, Ercheng,He, Min,Chen, Li,Yu, Pingzhong.

[8]Some characteristics of cool weather-tolerant rice varieties in Yunnan Province, China. Tanno, H,Xiong, JH,Dai, LY,Ye, CR.

[9]THE EFFECTS OF 2IP AND 2,4-D ON RICE CALLI DIFFERENTIATION. Zhu, YX,Ouyang, WJ,Li, Y,Chen, ZL.

[10]Crop acquisition of phosphorus, iron and zinc from soil in cereal/legume intercropping systems: a critical review. Xue, Yanfang,Xia, Haiyong,Xia, Haiyong,Zhang, Zheng,Christie, Peter,Li, Long,Tang, Caixian.

[11]CONSEQUENCES OF VARIED PLANTING GEOMETRY AND EARLY POST EMERGENCE HERBICIDES FOR CROP-WEED INTERVENTIONS IN RICE UNDER SEMI-ARID CLIMATE. Ashraf, U.,Mo, Z. W.,Tang, X. R.,Ashraf, U.,Mo, Z. W.,Tang, X. R.,Abbas, R. N.,Anjum, S. A.,Khan, I.,Hussain, S.. 2016

[12]Performance comparison of dispersive solid-phase extraction and multiplug filtration cleanup methods for the determination of tefuryltrione in plant and environmental samples using UHPLC-MS/MS. Yu, Yang,Ji, Mingshan,Tao, Yan,Dong, Fengshou,Xu, Jun,Liu, Xingang,Wu, Xiaohu,Zheng, Yongquan. 2017

[13]The synergistic toxicity of the multiple chemical mixtures: Implications for risk assessment in the terrestrial environment. Chen, Chen,Qian, Yongzhong,Chen, Chen,Qian, Yongzhong,Wang, Yanhua,Zhao, Xueping,Wang, Qiang.

[14]Phytotoxicity of atrazine to emergent hydrophyte, Iris pseudacorus L.. Wang, Qinghai,Li, Cui,Xiao, Bo,Que, Xiaoe.

[15]Simultaneous determination of three herbicides in wheat, wheat straw, and soil using a quick, easy, cheap, effective, rugged, and safe method with ultra high performance liquid chromatography and tandem mass spectrometry. Xu, Jun,Dong, Fengshou,Liu, Xingang,Wu, Xiaohu,Zheng, Yongquan,Zhao, Huanhuan,Wu, Yanbing.

[16]Toxicity assessment of 45 pesticides to the epigeic earthworm Eisenia fetida. Zhao, Xueping.

[17]Mechanism of Fenoxaprop-&ITP&IT-ethyl Resistance in Italian Ryegrass (&ITLolium&IT &ITperenne&IT ssp &ITmultiflorum&IT) from China. Zhang, Pei,Wu, Han,Gao, Yuan,Zhang, Wei,Dong, Liyao,Xu, Hongle.

[18]Determination of twelve herbicides in tobacco by a combination of solid-liquid-solid dispersive extraction using multi-walled carbon nanotubes, dispersive liquid-liquid micro-extraction, and detection by GC with triple quadrupole mass spectrometry. Liao, Qie Gen,Zhou, Yao Min,Luo, Lin Guang,Wang, Li Bing,Feng, Xiao Hu.

[19]Individual and Joint Toxicity of Three Chloroacetanilide Herbicides to Freshwater Cladoceran Daphnia carinata. He, Hongzhi,Chen, Guikui,Yu, Jing,He, Jinbo,Huang, Xiaolong,Li, Shufeng,Guo, Qiu,Yu, Tianhong,Li, Huashou,Yu, Jing.

[20]Determination of flavomycin residue in grass carp by high performance liquid chromatography. Tian Liang-liang,Huang Dong-mei,Shi Yong-fu,Han Feng,Zhou Peng. 2015

作者其他论文 更多>>

微信小程序