A multiresidue analytical method for the detection of seven triazolopyrimidine sulfonamide herbicides in cereals, soybean and soil using the modified QuEChERS method and UHPLC-MS/MS

文献类型： 外文期刊

第一作者： Xu, Jun

作者： Xu, Jun;Zhang, Jingge;Dong, Fengshou;Liu, Xingang;Zheng, Yongquan;Zhub, Guangyan

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期刊名称：ANALYTICAL METHODS （ 影响因子：2.896； 五年影响因子：2.716 ）

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收录情况： SCI

摘要： The combined use of modified QuEChERS extraction and ultra high-performance chromatography-tandem mass spectrometry (UHPLC-MS/MS) for determining all seven triazolopyrimidine sulfonamide herbicides in cereals (wheat, rice, and corn), soybean and soil was developed. The seven herbicides (metosulam, flumetsulam, pyroxsulam, florasulam, diclosulam, cloransulam-methyl and penoxsulam) were extracted using acetonitrile from five matrices, and then cleaned up using octadecylsilane or Florisil prior to UHPLC-MS/MS. The method has excellent linearity (R-2 >= 0.996). The average recoveries in wheat, rice, corn, soybean and soil at three spiked concentrations (0.005, 0.010 and 0.10 mg kg(-1)) ranged from 73.8% to 113.2% with all RSD values less than 17.5%. The LOQs for seven herbicides were 0.005 mg kg(-1) in cereals, soybean and soil. This method has been demonstrated to be reliable and convenient for monitoring triazolopyrimidine sulfonamide herbicides.

分类号： O65

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