Effective Monitoring of Fluxapyroxad and Its Three Biologically Active Metabolites in Vegetables, Fruits, and Cereals by Optimized QuEChERS Treatment Based on UPLC-MS/MS

文献类型： 外文期刊

第一作者： Dong, Fengshou

作者： Dong, Fengshou;Xu, Jun;Liu, Xingang;Wu, Xiaohu;Zheng, Yongquan

作者机构：

关键词： fluxapyroxad;metabolites;QuEChERS;UPLC-MS/MS

期刊名称：JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY （ 影响因子：5.279； 五年影响因子：5.269 ）

ISSN：

年卷期：

页码：

收录情况： SCI

摘要： Qualitative analysis and quantification of pesticide residues in foodstuff are essential to our health in daily life, especially regarding their metabolites, which may be more toxic and persistent. Thus, a valid analytical measure for detection of fluxapyroxad and its three metabolites (M700F002 (C-2), M700F008 (C-8), M700F048 (C-48)) in vegetables (cucumber, tomato, and pepper), fruits (grape, apple), and cereals (wheat, rice) was developed by UPLC-MS/MS with negative ion mode. The target compounds were extracted by acetonitrile contain 0.2% formic acid (v/v), and the extractions were cleaned up by octadecylsilane sorbents. The limits of quantitation and quantification were less than 0.14 mu g kg(-1) and 0.47 mu g kg(-1) in seven matrices. Furthermore, recoveries at levels of 0.01, 0.05, and 0.1 mg kg(-1) ranged from 74.9% to 110.5% with relative standard deviations <= 15.5% (n = 5). The method is validated to be effective and robust for the routine supervising of fluxapyroxad and its metabolites.

分类号： R15`S

  • 相关文献

[1]Simultaneous determination of three pesticides and their metabolites in unprocessed foods using ultraperformance liquid chromatography-tandem mass spectrometry. Wu, Xiaohu,Xu, Jun,Dong, Fengshou,Liu, Xingang,Pan, Xinglu,Du, Pengqiang,Wei, Dongmei,Zheng, Yongquan,Rong, Lili,Zheng, Yongquan. 2018

[2]A statistical approach to determine fluxapyroxad and its three metabolites in soils, sediment and sludge based on a combination of chemometric tools and a modified quick, easy, cheap, effective, rugged and safe method. Liu, Xingang,Zhu, Yulong,Dong, Fengshou,Xu, Jun,Zheng, Yongquan,Li, Minmin.

[3]Facile synthesis of amine-functional reduced graphene oxides as modified quick, easy, cheap, effective, rugged and safe adsorbent for multi-pesticide residues analysis of tea. Ma, Guicen,Zhang, Minglu,Zhu, Li,Chen, Hongping,Liu, Xin,Lu, Chengyin,Ma, Guicen,Zhang, Minglu,Zhu, Li,Chen, Hongping,Liu, Xin,Lu, Chengyin,Ma, Guicen,Zhang, Minglu,Zhu, Li,Chen, Hongping,Liu, Xin,Lu, Chengyin. 2018

[4]Simultaneous determination of cyflumetofen and its main metabolite residues in samples of plant and animal origin using multi-walled carbon nanotubes in dispersive solid-phase extraction and ultrahigh performance liquid chromatography-tandem mass spectrometry. Liu, Xingang,Dong, Fengshou,Xu, Jun,Li, Yuanbo,Zheng, Yongquan,Li, Minmin,Kong, Zhiqiang. 2013

[5]Simultaneous determination of 14 antiviral drugs and relevant metabolites in chicken muscle by UPLC-MS/MS after QuEChERS preparation. Qian, Yongzhong,Qiu, Jing.

[6]Simultaneous determination of oxathiapiprolin and two metabolites in fruits, vegetables and cereal using a modified quick, easy, cheap, effective, rugged, and safe method and liquid chromatography coupled to tandem mass spectrometry. Xu, Jun,Dong, Fengshou,Liu, Xingang,Li, Yuanbo,Zheng, Yongquan. 2014

[7]Development and validation of an ultra performance liquid chromatography Q-Exactive Orbitrap mass spectrometry for the determination of fipronil and its metabolites in tea and chrysanthemum. Liu, Xin,Lu, Chengyin. 2018

[8]Determination of Amicarbazone and Its Metabolites in Corn and Its Plant with a Modified QuEChERS by Liquid Chromatography-Tandem Mass Spectrometry. Dong Mao-Feng,Bai Bing,Tang Hong-Xia,Wang Wei-Min,Zhao Zhi-Hui,Han Zheng,Song Wei-Guo. 2015

[9]Simultaneous determination of spirotetramat and its four metabolites in fruits and vegetables using a modified quick, easy, cheap, effective, rugged, and safe method and liquid chromatography/tandem mass spectrometry. Liu, Xingang,Xu, Jun,Dong, Fengshou,Liang, Xuyang,Li, Minmin,Zheng, Yongquan,Duan, Lifang.

[10]Determination and Dissipation of Fipronil and Its Metabolites in Peanut and Soil. Li, Minghui,Li, Puyu,Wang, Lin,Feng, Mengyuan,Han, Lijun,Li, Minghui,Wang, Lin.

[11]Degradation of Fluxapyroxad in Soils and Water/Sediment Systems Under Aerobic or Anaerobic Conditions. Liu, Xingang,Chen, Chao,Dong, Fengshou,Xu, Jun,Zheng, Yongquan.

[12]Concentrations and dissipation of difenoconazole and fluxapyroxad residues in apples and soil, determined by ultrahigh-performance liquid chromatography electrospray ionization tandem mass spectrometry. Jia, Chunhong,Zhao, Ercheng,Chen, Li,Yu, Pingzhong,Jing, Junjie,He, Min,Zheng, Yongquan.

[13]Impact of fluxapyroxad on the microbial community structure and functional diversity in the silty-loam soil. Xu Jun,Liu Yong-zhuo,Dong Feng-shou,Liu Xin-gang,Zhang Wen-wen,Zheng Yong-quan. 2015

[14]Determination of virginiamycin M1 residue in tissues of swine and chicken by ultra-performance liquid chromatography tandem mass spectrometry. Wang, Xiaoyang,Wang, Mi,Zhang, Keyu,Hou, Ting,Zhang, Lifang,Fei, Chenzong,Xue, Feiqun,Wang, Xiaoyang,Hang, Taijun. 2018

[15]Rapid Determination of Organonitrogen, Organophosphorus and Carbamate Pesticides in Tea by Ultrahigh-Performance Liquid Chromatography-Tandem Mass Spectrometry (UPLC-MS/MS). Zhao, Hong-Xia,Yang, Guo-Sheng,Zhao, Shan-Cang,Deng, Li-Gang,Mao, Jiang-Sheng,Guo, Chang-Ying,Lu, Xiao,Zhao, Shan-Cang,Deng, Li-Gang,Mao, Jiang-Sheng,Guo, Chang-Ying,Lu, Xiao,Zhao, Shan-Cang,Deng, Li-Gang,Mao, Jiang-Sheng,Guo, Chang-Ying,Lu, Xiao,Aboul-Enein, Hassan Y.. 2013

[16]Determination of difenoconazole residue in tomato during home canning by UPLC-MS/MS. Dong, Fengshou,Xu, Jun,Liu, Xingang,Li, Jing,Li, Yuanbo,Chen, Xiu,Zheng, Yongquan,Zhang, Changpeng,Shan, Weili. 2012

[17]Transformation of deoxynivalenol and its acetylated derivatives in Chinese steamed bread making, as affected by pH, yeast, and steaming time. Wang, Bujun.

[18]Determination of Herbicide Propisochlor in Soil, Water and Rice by Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) Method Using by UPLC-ESI-MS/MS. Xu, Jun,Liu, Xingang,Dong, Fengshou,Zheng, Yongquan,Wu, Yanbing,Zhang, Ying.

[19]Validation of a confirmatory method of salbutamol in sheep hair by UPLC-MS/MS and its application to pharmacokinetic study. Suo Decheng,Zhang Wei,Zhang Yu,Zhao Genlong,Wang Ruigou,Wang PeiLong,Su Xiaoou.

[20]Determination of chlorantraniliprole residues in corn and soil by UPLC-ESI-MS/MS and its application to a pharmacokinetic study. Xu, Jun,Liu, Xingang,Li, Jing,Li, Yuanbo,Kong, Zhiqiang,Zheng, Yongquan,Shan, Weili,Zheng, Zuntao.

作者其他论文 更多>>

微信小程序