Detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramic

文献类型: 外文期刊

第一作者: Liao, Chang-Zhong

作者: Liao, Chang-Zhong;Liu, Chengshuai;Li, Fangbai;Liao, Chang-Zhong;Shih, Kaimin;Tang, Yuanyuan;Liu, Chengshuai;Lee, Po-Heng

作者机构:

关键词: Detoxification;Immobilization;Chromite ore processing residue (COPR);Glass-ceramic;Rietveld quantitative XRD

期刊名称:JOURNAL OF HAZARDOUS MATERIALS ( 影响因子:10.588; 五年影响因子:10.129 )

ISSN:

年卷期:

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收录情况: SCI

摘要: A promising strategy for the detoxification and immobilization of chromite ore processing residue (COPR) in a spinel-based glass-ceramic matrix is reported in this study. In the search for a more chemically durable matrix for COPR, the most critical crystalline phase for Cr immobilization was found to be a spinel solid solution with a chemical composition of MgCr1.32Fe0.19Al0.49O4. Using Rietveld quantitative X-ray diffraction analysis, we identified this final product is with the phases of spinel (3.5 wt.%), diopside (5.2 wt.%), and some amorphous contents (91.2 wt.%). The partitioning ratio of Cr reveals that about 77% of the Cr was incorporated into the more chemically durable spinel phase. The results of Cr K-edge X-ray absorption near-edge spectroscopy show that no Cr(VI) was observed after conversion of COPR into a glass-ceramic, which indicates successful detoxification of Cr(VI) into Cr(III) in the COPR-incorporated glass-ceramic. The leaching performances of Cr2O3 and COPR-incorporated glass-ceramic were compared with a prolonged acid-leaching test, and the results demonstrate the superiority of the COPR-incorporated glass-ceramic matrix in the immobilization of Cr. The overall results suggest that the use of affordable additives has potential in more reliably immobilizing COPR with a spinel-based glass-ceramic for safer disposal of this hazardous waste. (C) 2016 Elsevier B.V. All rights reserved.

分类号: TB1

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