Trichoderpyrone, a Unique Polyketide Hybrid with a Cyclopentenone-Pyrone Skeleton from the Plant Endophytic Fungus Trichoderma gamsii
文献类型： 外文期刊
第一作者： Chen, Lin
作者： Chen, Lin;Ding, Gang;Yu, Meng;Wang, Meng-hua;Li, Lu-ying;Zhang, Tao;Jia, Hong-Mei;Zhang, Hong-wu;Shang, Hai;Zou, Zhong-mei;Chen, Lin;Ding, Gang;Yu, Meng;Wang, Meng-hua;Li, Lu-ying;Zhang, Tao;Jia, Hong-Mei;Zhang, Hong-wu;Shang, Hai;Zou, Zhong-mei;Niu, Shu-Bin;Li, Li;Zhang, Gui-shan;Liu, Xing-zhong;Chen, Lin
作者机构：
期刊名称：JOURNAL OF NATURAL PRODUCTS （ 影响因子：4.05； 五年影响因子：4.603 ）
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年卷期：
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收录情况： SCI
摘要： Trichoderpyrone (1), a unique polyketide with a cyclopentenone-pyrone hybrid skeleton, was isolated from the plant endophytic fungus Trichoderma gamsii. The structure of 1 was determined by detailed analysis of NMR data together with comparison of chemical shift values of similar fragments. The relative and absolute configurations were established by NOESY correlations and CD experiment. Trichoderpyrone (1) displayed weak cytotoxic activities against A549, HepG2, and HeLa cancer cell lines. 1 might originate from a hybrid biosynthetic pathway through two nonreduced (NR) polyketide megasynthetases.
分类号： R93
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