Accelerated spent coffee grounds humification by heat/base co-activated persulfate and products' fertilization evaluation
文献类型: 外文期刊
第一作者: Zhu, Yanping
作者: Zhu, Yanping;Zhang, Keyi;Hu, Qing;Liu, Weijia;Qiao, Yi;Cai, Dongqing;Wang, Dongfang;Xu, He;Shu, Shihu;Zhu, Pengjin;Gao, Naiyun
作者机构:
关键词: Artificial humification; Persulfate-based advanced oxidation; Biowaste; Fulvic acid; Fertilization effect
期刊名称:ENVIRONMENTAL TECHNOLOGY & INNOVATION ( 影响因子:7.1; 五年影响因子:6.9 )
ISSN: 2352-1864
年卷期: 2023 年 32 卷
页码:
收录情况: SCI
摘要: Coffee, as the second most common beverage in the world, produced 60% of spent coffee grounds (SCG) with per ton of coffee beans processed. SCG is a typical lignocellulosic-rich organic waste and mainly disposed via composting or incineration. In this study, a rapid humification approach was proposed for the recycling of SCG using heat/base co-activated persulfate (heat/KOH/PS) advanced oxidation process. The yields of humic-like acid (HLA) and fulvic-like acid (FLA) reached 45 (3.96%) and 192 mg/g (19.2%) under the optimal humification conditions of 1% PS and 4% KOH at 100 celcius in 1 h. The typical active groups of-OH and-COOH in FA standard were observed with higher amounts in the product compared to SCG, which may be related to occurrence of hydroxylation, carboxylation and Maillard reactions during humification. Radicals of center dot OH and SO4 center dot-were identified in heat/KOH/PS system and made significant contribution to SCG humification. A slow-release nano FLA fertilizer (SNFF) was prepared by mixing treated SCG with attapulgite and showed good slow-release behaviors of HLA and FLA. In pot experiments with acid soil, SNFF increased the average root length of chickweeds by 233% compared with blank. Meanwhile, SNFF also contributed to increased abundance and richness of soil microbial community as well as a pH rise from 5 to 6.7, which was conducive to acid soil amendment. The earthworm test indicated positive ecological safety of SNFF. Overall, this study highlights an efficient humification method for the recycling of organic biowaste such as SCG in green agriculture.
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