Reduction and alkylation of (eta(6)-arene)tricarbonylmanganese complexes using alkyl-substituted coenzyme NADH models
文献类型： 外文期刊
第一作者： Zheng, Li
作者： Zheng, Li;Huang, Qiliang;Cao, Lidong
作者机构：
关键词： (eta(6)-arene)tricarbonylmangenese complexes;Coenzyme NADH models;Radical addition;Alkyl transfer
期刊名称：JOURNAL OF ORGANOMETALLIC CHEMISTRY （ 影响因子：2.369； 五年影响因子：2.018 ）
ISSN： 0022-328X
年卷期： 2014 年 768 卷
页码：
收录情况： SCI
摘要： The direct tert-butyl group transfer was observed between t-BuBNAH and (eta(6)-arene)Mn(CO)(3)(+) complexes in reflux acetonitrile without a radical initiator, and the corresponding tert-butyl radical addition products were achieved. The substituents on the aromatic ring significantly influence the reactivity and chemoselectivity. The electron-withdrawing group helps to promote the reactions. The radical inhibition experiment indicated that the reaction is probably a radical chain process initiated by single electron transfer. (C) 2014 Elsevier B.V. All rights reserved.
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