Fast determination of alkylphenol ethoxylates in leafy vegetables using a modified quick, easy, cheap, effective, rugged, and safe method and ultra-high performance supercritical fluid chromatography-tandem mass spectrometry

文献类型： 外文期刊

第一作者： Jiang, Ze-Jun

作者： Jiang, Ze-Jun;Cao, Xiao-Lin;Li, Hui;Zhang, Chan;Jin, Fen;Shao, Hua;Jin, Mao-Jun;Wang, Shan-Shan;She, Yong-Xin;Wang, Jing;Jiang, Ze-Jun;Cao, Xiao-Lin;Li, Hui;Zhang, Chan;Jin, Fen;Shao, Hua;Jin, Mao-Jun;Wang, Shan-Shan;She, Yong-Xin;Wang, Jing;Abd El-Aty, A. M.;Abd El-Aty, A. M.

作者机构：

关键词： Alkylphenol ethoxylates;Ultra-high performance supercritical fluid;chromatography-tandem mass;spectrometry (UHPSFC-MS/MS);Leafy vegetable;QuEChERS;Background contamination;Residue determination

期刊名称：JOURNAL OF CHROMATOGRAPHY A （ 影响因子：4.759； 五年影响因子：4.302 ）

ISSN： 0021-9673

年卷期： 2017 年 1525 卷

页码：

收录情况： SCI

摘要： In the present study, a quick and sensitive method was developed for simultaneous determination of nonylphenol ethoxylates (NPxEOs) and octylphenol ethoxylates (OPxEOs) (x=2-20) in three leafy vegetables, including cabbage, lettuce, and spinach using a modified "QuEChERS" method and ultra-high performance supercritical fluid chromatography-tandem mass spectrometry (UHPSFC-MS/MS) with scheduled multiple reaction monitoring (MRM). Under optimized conditions, the 38 target analytes were analyzed within a short period of time (5 min). The linearities of the matrix-matched standard calibrations were satisfactory with coefficients of determination (R-2)>0.99 and the limits of detection (LOD) and quantification (LOQ) were in between 0.02-0.27 and 0.18-1.75 mu g kg(-1), respectively. The recovery of all target analytes spiked at three (low, medium, and high) fortification levels in various leafy vegetables were ranged from 72.8-122.6% with relative standard deviation (RSD) <= 18.3%. The method was successfully applied to market samples and the target analytes were found in all monitored samples, with total concentrations of 0-8.67 mu g kg(-1) and 15.75-95.75 mu g kg(-1) for OPxEOs and NPxEOs (x=2-20), respectively. In conclusion, the newly developed UHPSFC-ESI-MS/MS method is rapid and versatile and could be extrapolated for qualitative and quantitative analysis of APxEOs in other leafy vegetables. (C) 2017 Elsevier B.V. All rights reserved.

分类号：

  • 相关文献

[1]Development of "one-pot" method for multi-class compounds in porcine formula feed by multi-function impurity adsorption cleaning followed ultra-performance liquid chromatography-tandem mass spectrometry detection. Wang, Peilong,Wang, Xiao,Zhang, Wei,Su, Xiaoou,Wang, Peilong,Wang, Xiao,Zhang, Wei,Su, Xiaoou.

[2]Dynamic residual pattern of azoxystrobin in Swiss chard with contribution to safety evaluation. Farha, Waziha,Rahman, Md. Musfiqur,Kabir, Md. Humayun,Chung, Hyung Suk,Lee, Han Sol,Shim, Jae-Han,Abd El-Aty, A. M.,Abd El-Aty, A. M.,Shin, Ho-Chul,Jeon, Jong-Sup,Wang, Jing,Chang, Byung-Joon. 2018

[3]DISSIPATION AND RESIDUE DETERMINATION OF PENFLUFEN IN SOIL BY UPLC-MS-MS. Han, Ping,Gene, Qianqian,Zhangl, Wenbing,Cao, Yongsong,Han, Ping,Mae, Shuai,Feng, Xiaoyuan. 2017

[4]Residual dynamic and risk assessment of dimethomorph in Swiss chard grown at two different sites. Kabir, Md. Humayun,Rahman, Md. Musfiqur,Chung, Hyung Suk,Lee, Han Sol,Shim, Jae-Han,Abd El-Aty, A. M.,Abd El-Aty, A. M.,Shin, Ho-Chul,Kim, Mi-Ra,Chang, Byung-Joon,Wang, Jing. 2018

[5]Quantitative Analysis of 10 Mycotoxins in Wheat Flour by Ultrahigh Performance Liquid Chromatography-Tandem Mass Spectrometry with a Modified QuEChERS Strategy. Zhou, Qingxin,Li, Fenghua,Chen, Leilei,Jiang, Dafeng,Li, Fenghua,Jiang, Dafeng. 2016

[6]A rapid and simple HPLC-FLD screening method with QuEChERS as the sample treatment for the simultaneous monitoring of nine bisphenols in milk. Xiong, Lin,Yan, Ping,Chu, Min,Gao, Ya-Qin,Li, Wei-Hong,Yang, Xiao-Ling,Xiong, Lin,Yan, Ping,Gao, Ya-Qin,Li, Wei-Hong,Yang, Xiao-Ling,Yan, Ping,Chu, Min. 2018

[7]QuEChERS in Combination with Ultrasound-Assisted Dispersive Liquid-Liquid Microextraction Based on Solidification of Floating Organic Droplet Method for the Simultaneous Analysis of Six Fungicides in Grape. You, Xiangwei,Jiang, Wenqing,Liu, Fengmao,Liu, Congyun. 2013

[8]Dissipation kinetics and residue of LH-2010A in cucumber and soil under greenhouse condition. Li, Ruijuan,Liu, Tongjin,Song, Guochun,Li, Rumei,Yu, Jianlei. 2015

[9]Development and validation of a multiclass method for the quantification of veterinary drug residues in honey and royal jelly by liquid chromatography-tandem mass spectrometry. Jin, Yue,Zhang, Jinzhen,Zhao, Wen,Zhang, Wenwen,Wang, Lin,Zhou, Jinhui,Li, Yi,Jin, Yue,Zhang, Jinzhen,Zhao, Wen,Wang, Lin,Zhou, Jinhui,Li, Yi,Jin, Yue,Zhang, Jinzhen,Zhao, Wen,Wang, Lin,Zhou, Jinhui,Li, Yi. 2017

[10]Determination of Niclosamide in Aquatic Animal Tissue by a Novel Extraction Procedure and High-Performance Liquid Chromatography-Heated Electrospray Ionization-Tandem Mass Spectrometry. Liu, Yongtao,Ai, Xiaohui,Yang, Qiuhong,Yang, Hong,Xu, Ning,Liu, Yongtao,Wang, Fuhua,Liu, Yongtao,Ai, Xiaohui,Xu, Ning,Suo, Wenwen. 2015

[11]Determination of 4 Pesticides Residues in Citrus and Essential Oil by Ultra Performance Liquid Chromatography-Mass Spectrometry. Kong Zhi-Qiang,Dong Feng-Shou,Liu Xin-Gang,Xu Jun,Zheng Yong-Quan,Gong Yong,Shan Wei-Li. 2012

[12]Determination and risk assessment of sixteen polycyclic aromatic hydrocarbons in vegetables. Li, Huidong,Lu, Xiao,Du, Hongxia,Guan, Shuai,Chen, Zilei,Li, Huidong,Zhu, Duanwei,Li, Huidong,Lu, Xiao,Du, Hongxia,Guan, Shuai,Chen, Zilei. 2018

[13]Effective Monitoring of Fluxapyroxad and Its Three Biologically Active Metabolites in Vegetables, Fruits, and Cereals by Optimized QuEChERS Treatment Based on UPLC-MS/MS. Dong, Fengshou,Xu, Jun,Liu, Xingang,Wu, Xiaohu,Zheng, Yongquan.

[14]A multi-residue method for the determination of pesticides in tea using multi-walled carbon nanotubes as a dispersive solid phase extraction absorbent. Lei, ShaoRong,Qiu, ShiTing,Guo, LingAn,Yi, ShengGuo,Liu, Wei,Hou, Xue,Hou, Xue.

[15]Determination of Persistent Environmental Pollutants in Bee Pollen by Gas Chromatography-Mass Spectrometry Using a Modified QuEChERS Approach. Wei, Yue,Chen, Fang,Xue, Xiaofeng,Li, Yi,Jinhuizhou,Zhao, Liuwei,Cao, Weirui,Wu, Liming,Wei, Yue,Chen, Fang,Xue, Xiaofeng,Li, Yi,Jinhuizhou,Zhao, Liuwei,Cao, Weirui,Wu, Liming,Yu, Linsheng.

[16]Enantioseparation and determination of isofenphos-methyl enantiomers in wheat, corn, peanut and soil with Supercritical fluid chromatography/tandem mass spectrometric method. Dong, Fengshou,Xu, Jun,Liu, Xingang,Chen, Zenglong,Liu, Na,Zheng, Yongquan.

[17]Analysis of 13 kinds of steroid hormones in raw milk using modified QuEChERS method combined with UPLC-QTOF-MS. Tan Xin-tong,Wang Ming-lin,Li Zeng-mei,Deng Li-gang,Zhao Shan-cang,Li Zeng-mei,Deng Li-gang,Zhao Shan-cang. 2016

[18]Facile synthesis of amine-functional reduced graphene oxides as modified quick, easy, cheap, effective, rugged and safe adsorbent for multi-pesticide residues analysis of tea. Ma, Guicen,Zhang, Minglu,Zhu, Li,Chen, Hongping,Liu, Xin,Lu, Chengyin,Ma, Guicen,Zhang, Minglu,Zhu, Li,Chen, Hongping,Liu, Xin,Lu, Chengyin,Ma, Guicen,Zhang, Minglu,Zhu, Li,Chen, Hongping,Liu, Xin,Lu, Chengyin. 2018

[19]Development and validation of an ultra performance liquid chromatography Q-Exactive Orbitrap mass spectrometry for the determination of fipronil and its metabolites in tea and chrysanthemum. Liu, Xin,Lu, Chengyin. 2018

[20]Use of isoquinoline alkaloids as markers for identification of honey and pollen from Macleaya cordata (Willd.) R. Br. Zhao, Lingling,Liang, Xinwen,Wu, Liming,Xue, Xiaofeng,Wu, Liming,Xue, Xiaofeng,Zhang, Zhongyin,Zhao, Lingling,Cao, Wei. 2018

作者其他论文 更多>>

微信小程序