Study on the synthesis of polyacrolein o-carboxyl phenylhydrazone chelating resin and its adsorption properties

文献类型: 外文期刊

第一作者: Ge, XP

作者: Ge, XP;Zhang, BW

作者机构:

关键词: chelating resins;adsorption;polyacrolein-styrene resin;polyacrolein-o-carbxyl phenylhydrazone resin;precious metals;IR spectra

期刊名称:SPECTROSCOPY AND SPECTRAL ANALYSIS ( 影响因子:0.589; 五年影响因子:0.504 )

ISSN: 1000-0593

年卷期: 2003 年 23 卷 6 期

页码:

收录情况: SCI

摘要: A new chelating resin containing o-carbxyl phenylhydrazone as functional group was synthesized through the reaction of o-carbxyl phenyl hydrazine chelating agent with the active aldehyde on the polymer matrix of macroporous acrolein-styrene copolymer. The structure of the poly-acrolein o-carbxyl phenylhydrazone resin was proved by means of the elementary analysis and the infrared (IR) spectra. Its adsorption properties toward noble metal ions were investigated through ICP-AES, showing that the resin can selectively adsorb gold, palladium and platinum, whose exchange capacities are 1.98, 0.31, 0.16 mmol(.)g(-1), respectively, for dry resin.

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