Determination of Imidacloprid and Its Three Metabolites in Honey and Bee Pollen by Liquid Chromatography- Tandem Mass Spectrometry

文献类型： 外文期刊

第一作者： Liang Xiu-Mei

作者： Liang Xiu-Mei;Wang Xiang-Yun;Qi Pei-Pei;Liu Zhen-Zhen;Liu Zhi-Wei;Zhou Li;Wang Xin-Quan;Wang Qiang;Liang Xiu-Mei;Wang Xiang-Yun;Xue Xiao-Feng

作者机构：

关键词： Liquid chromatography tandem mass spectrometry;Honey;Hollen;Imidacloprid;Imidacloprid olefin;Imidacloprid urea;6-Chloronicotinic acid;Enhanced matrix removal-Lipid

期刊名称：CHINESE JOURNAL OF ANALYTICAL CHEMISTRY （ 影响因子：1.134； 五年影响因子：0.909 ）

ISSN： 0253-3820

年卷期： 2017 年 45 卷 4 期

页码：

收录情况： SCI

摘要： A method was developed for the determination of imidacloprid and its metabolites imidacloprid olefin, imidacloprid urea and 6-chloronicotinic acid in honey and bee pollen by liquid chromatography tandem mass spectrometry (LC-MS/MS). On the basis of typical QuEChERS method, the pH and times of extraction solvent, sorbents were optimized to ensure the extraction efficiency and the purification of extraction. Finally, the method was developed as follows: matrix was extracted with 5% formic acid. acetonitrile twice, and the extraction was cleaned with enhanced matrix removal. lipid (EMR), detected with LC-MS/MS and quantified with external matrix standards. The results indicated that the average spiked recoveries of imidacloprid, imidacloprid olefin, imidacloprid urea and 6. chloronicotinic acid in honey and pollen samples were 86.0% - 111.5% with relative standard deviations (RSDs) of 1.7% -9.6%, the LODs were 0.20, 3.50, 0.40 and 14.00. mu/kg, and the LOQs were 0.60, 11.64, 1.20 and 45.00. mu/kg. The method was rapid and simple with high sensitivity and good reproducibility, and suitable for the determination of imidacloprid and its three metabolites residues in honey and bee pollen.

分类号：

  • 相关文献

[1]Evaluation of transfer rates of multiple pesticides from green tea into infusion using water as pressurized liquid extraction solvent and ultra-performance liquid chromatography tandem mass spectrometry. Chen, Hongping,Liu, Xin,Lu, Chengyin,Chen, Hongping,Pan, Meiling,Liu, Xin,Lu, Chengyin,Chen, Hongping,Liu, Xin,Lu, Chengyin. 2017

[2]Simultaneous determination of atropine and scopolamine in buckwheat and related products using modified QuEChERS and liquid chromatography tandem mass spectrometry. Chen, Hongping,Marin-Saez, Jesus,Romero-Gonzalez, Roberto,Garrido Frenich, Antonia,Chen, Hongping. 2017

[3]Determination of Ethiprole Enantiomers Residue in Rices Using Solid Phase Extraction-Liquid Chromatography Tandem Mass Spectrometry. Zhang Hu,Wang Ming-Hua,Zhang Hu,Qian Ming-Rong,Wang Xiang-Yun,Xu Hao,Qi Pei-Pei,Liu Fei. 2012

[4]A liquid chromatography tandem mass spectrometry method for simultaneous determination of acid/alkaline phytohormones in grapes. Liu, Hong,Han, Zheng,Liu, Gang,Rao, Qinxiong,Bai, Bing,Zhao, Zhihui,Wu, Aibo.

[5]Development and validation of a multiclass method for the quantification of veterinary drug residues in honey and royal jelly by liquid chromatography-tandem mass spectrometry. Jin, Yue,Zhang, Jinzhen,Zhao, Wen,Zhang, Wenwen,Wang, Lin,Zhou, Jinhui,Li, Yi,Jin, Yue,Zhang, Jinzhen,Zhao, Wen,Wang, Lin,Zhou, Jinhui,Li, Yi,Jin, Yue,Zhang, Jinzhen,Zhao, Wen,Wang, Lin,Zhou, Jinhui,Li, Yi. 2017

[6]Application of ICP-MS to detection of trace elements and heavy metals in different kinds of honey. Rui Yu-kui,Chen Lan-zhen,Zhao Jing,Xue Xiao-feng,Wang Peng,Ye Zhi-hua. 2008

[7]FATAL HONEY POISONING IN SOUTHWEST CHINA: A CASE SERIES OF 31 CASES. Zhang, Qiang,Li, Juanjuan,Yu, Siyang,Liu, Hui,Liu, Zhitao,Zhang, Qiang,Chen, Xinguang,Chen, Shunan,Ye, Yinlong,Luo, Jiancheng. 2017

[8]Rapid and sensitive determination of two degradation products of flumethrin in honey by ultrasonically assisted extraction and gas chromatography with electron capture detection. Zhou, Jinhui,Xue, Xiaofeng,Li, Yi,Zhang, Jinzhen,Wu, Liming,Chen, Lanzhen,Zhao, Jing.

[9]Determination of organochlorine pesticides in propolis by gas chromatography-electron capture detection using double column series solid-phase extraction. Chen, Fang,Chen, Lanzhen,Zhou, Jinhui,Xue, Xiaofeng,Zhao, Jing,Wang, Qiang.

[10]Detection of honey adulteration by high fructose corn syrup and maltose syrup using Raman spectroscopy. Ling, Guowei,Shan, Yang,Zhu, Xiangrong,Zhang, Xin. 2012

[11]Occurrence of erythromycin and its degradation products residues in honey. Validation of an analytical method. Zhao, Liuwei,Cao, Weirui,Xue, Xiaofeng,Wang, Miao,Wu, Liming,Yu, Linsheng.

[12]Classification of Chinese Honeys According to Their Floral Origins Using Elemental and Stable Isotopic Compositions. Wu, Zhaobin,Chen, Lanzhen,Wu, Liming,Xue, Xiaofeng,Zhao, Jing,Li, Yi,Chen, Lanzhen,Wu, Liming,Xue, Xiaofeng,Li, Yi,Ye, Zhihua,Lin, Guanghui,Lin, Guanghui.

[13]Analysis of maltooligosaccharides in honey samples by ultra-performance liquid chromatography coupled with evaporative light scattering detection. Zhou, Jinhui,Wu, Liming,Diao, Qingyun,Li, Yi,Zhao, Jing,Zhou, Jinhui,Wu, Liming,Li, Yi,Zhao, Jing,Zhou, Jinhui,Wu, Liming,Li, Yi,Zhao, Jing,Qi, Yitao,Ritho, Joan,Duan, Lili.

[14]Phenolics and abscisic acid identified in acacia honey comparing different SPE cartridges coupled with HPLC-PDA. Sun, Chunli,Tan, Hongbo,Zhang, Yuhao,Zhang, Hongcheng,Tan, Hongbo,Zhang, Hongcheng.

[15]Detection of adulterants such as sweeteners materials in honey using near-infrared spectroscopy and chemometrics. Shan, Yang,Li, Gaoyang,Su, Donglin,Liu, Feng,Li, Shuifang,Zhang, Zhuoyong.

[16]Determination of Alkaloids in Honey by Dispersive Solid Phase Extraction and High Performance Liquid Chromatography-Tandem Mass Spectrometry. Guo Wei-Hua,Zhou Jin-Hui,Huang Jing-Ping,Wang Peng,Li Yi. 2014

[17]Application of Inductively Coupled Plasma Mass Spectrometry with Chemometric Methods in Classification of Honeys According to Their Types. Wu Zhao-bin,Chen Fang,Chen Lan-zhen,Zhao Jing,Li Yi,Wu Li-ming,Chen Fang,Chen Lan-zhen,Li Yi,Wu Li-ming,Wu Zhao-bin,Chen Fang,Chen Lan-zhen,Zhao Jing,Li Yi,Wu Li-ming,Ye Zhi-hua. 2015

[18]Use of isoquinoline alkaloids as markers for identification of honey and pollen from Macleaya cordata (Willd.) R. Br. Zhao, Lingling,Liang, Xinwen,Wu, Liming,Xue, Xiaofeng,Wu, Liming,Xue, Xiaofeng,Zhang, Zhongyin,Zhao, Lingling,Cao, Wei. 2018

[19]Application of ICP-MS to Identify the Botanic Source of Characteristic Honey in South Yunnan. Wei Yue,Chen Fang,Wang Yong,Chen Lan-zhen,Wu Li-ming,Wei Yue,Chen Fang,Wang Yong,Chen Lan-zhen,Wu Li-ming,Zhang Xue-wen,Wang Yan-hui,Zhou Qun. 2016

[20]A modified FOX-1 method for Micro-determination of hydrogen peroxide in honey samples. Li, Dan,Wang, Meng,Cheng, Ni,Cao, Wei,Xue, Xiaofeng,Wu, Liming. 2017

作者其他论文 更多>>

微信小程序