Gold-Catalyzed Highly Regioselective Hydration of Alkynylsulfonamides for Atom-Economic Synthesis of N-Ketosulfonamides
文献类型： 外文期刊
第一作者： Wang, Yuguang
作者： Wang, Yuguang;Ma, Menghao;Deng, Yunlong;Yao, Panpan;Xing, Agui;Li, Wenjing;Chen, Yuan;Wu, Ji'an
作者机构：
关键词： atom-economic synthesis; gold-catalyzed; hydration; N-ketosulfonamides; regioselectivity
期刊名称：APPLIED ORGANOMETALLIC CHEMISTRY
ISSN： 0268-2605
年卷期： 2025 年 39 卷 2 期
页码：
收录情况： SCI
摘要： Gold(I)-catalyzed highly regioselective hydration of alkynylsulfonamides for synthesis of N-ketosulfonamides in 85%-96% yields. The reaction used water as a nucleophile, which had the advantages of mild reaction conditions, good functional group tolerance, high regioselectivity, high yield, and 100% atomic economy (without generating by-products or waste). This might endow this method with great potential in green synthesis of N-ketosulfonamides compounds.
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