文献类型： 外文期刊
第一作者： Cao, Lidong
作者： Cao, Lidong;Jimeno, Ciril;Renaud, Philippe;Cao, Lidong;Jimeno, Ciril
作者机构：
关键词： radical; atom transfer; ATRA-reaction; GTRA reaction; sulfur group transfer; thiosulfonates; chain reaction; thioalkylation; alkenes; sulfur dioxide
期刊名称：ADVANCED SYNTHESIS & CATALYSIS （ 影响因子：5.837； 五年影响因子：5.112 ）
ISSN： 1615-4150
年卷期： 2020 年 362 卷 17 期
页码：
收录情况： SCI
摘要： An efficient method for the thioalkylation of alkenes via radical desulfitative sulfur-group transfer is described. The reaction is based on the use of readily available thiosulfonates as starting materials and cheap radical initiators such as dilauroyl peroxide (DLP) and sun lamp irradiation. No transition metal catalyst is required, and the reaction takes place under mild conditions.
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