Analysis of hydroxylated polybrominated diphenyl ethers in plant samples using ultra performance liquid chromatography-mass spectrometry

文献类型: 外文期刊

第一作者: Wang Sen

作者: Wang Sen;Wu Tong;Huang HongLin;Zhang ShuZhen;Ping Hua;Lu AnXiang

作者机构:

关键词: OH-PBDE;plant extraction;ultra performance liquid chromatography;mass spectrometry

期刊名称:SCIENCE CHINA-CHEMISTRY ( 影响因子:9.445; 五年影响因子:5.238 )

ISSN: 1674-7291

年卷期: 2011 年 54 卷 11 期

页码:

收录情况: SCI

摘要: A method was developed for the analysis of hydroxylated brominated diphenyl ethers (OH-PBDEs) in plant samples using an ultra performance liquid chromatography-triple quadrupole mass spectrometer (UPLC-ESI-MS/MS) in negative mode. Plant samples were extracted and cleaned up through florisil column, resolved on a 100 mm C-18 column with linear gradient elution and detected by mass spectrometry in multiple reaction monitoring (MRM) mode. The method provided good recoveries ranging from 68.2% to 94.6%, relative standard deviation (RSD) in the range of 3.2%-9.1%, and limits of quantification (LOQ) defined as the signal-to-noise ratio of 10 of 0.3-2.1 ng/g. It allowed a fast separation and sensitive quantification of the isomers and homologues of seven OH-PBDE congeners 2'-OH-BDE-3, 3'-OH-BDE-7, 4'-OH-BDE-17, 3'-OH-BDE-28, 3-OH-BDE-47, 5-OH-BDE-47 and 6-OH-BDE-47. The method was successfully applied to identify and quantify the formation of hydroxylated metabolites in alfalfa exposed to BDE-209. Five OH-PBDEs were detected in plant tissues, and more congeners were found in roots than in shoots. To our knowledge, this work represents the first attempt to validate UPLC-MS/MS method to quantify OH-PBDEs in plant samples without derivatization.

分类号:

  • 相关文献

[1]UPLC-ESI-MS-MS Determination of Three beta(2)-Agonists in Pork. Zheng, Hong,Yang, Guo-Sheng,Deng, Li-Gang,Lu, Xiao,Zhao, Shan-Cang,Guo, Chang-Ying,Mao, Jiang-Sheng,Wang, Yu-Tao,Deng, Li-Gang,Lu, Xiao,Zhao, Shan-Cang,Guo, Chang-Ying,Mao, Jiang-Sheng,Wang, Yu-Tao,Yang, Guo-Sheng,Aboul-Enein, Hassan Y.,Aboul-Enein, Hassan Y.. 2010

[2]Determination of Tetracyclines and Their Epimers in Agricultural Soil Fertilized with Swine Manure by Ultra-High-Performance Liquid Chromatography Tandem Mass Spectrometry. Zheng Wen-li,Zhang Li-fang,Zhang Ke-yu,Wang Xiao-yang,Xue Fei-qun. 2012

[3]UPLC-ELSD determination of 1-octacosanol in raw material and health products. Xue, Xiaofeng,Chen, Lanzhen,Zhou, Jinhui,Wu, Liming,Li, Yi,Chen, Fang,Zhang, Jinzhen,Zhao, Jing,Xue, Xiaofeng,Xue, Xiaofeng,Chen, Lanzhen,Zhou, Jinhui,Wu, Liming,Li, Yi,Chen, Fang,Zhang, Jinzhen,Zhao, Jing.

[4]Ionic liquid-based ultrasonic/microwave-assisted extraction combined with UPLC for the determination of anthraquinones in rhubarb. Lu, Chunxia,Wang, Hongxin,Lv, Wenping,Ma, Chaoyang,Xu, Pao,Zhu, Jian,Xie, Jun,Liu, Bo,Zhou, Qunlan.

[5]Comparative analyses of secreted proteins from the phytopathogenic fungus Verticillium dahliae in response to nitrogen starvation. Jun Chu,Wei-Fang Li,Wang Cheng,Mo Lu,Ke-Hai Zhou,He-Qin Zhu,Fu-Guang Li,Cong-Zhao Zhou.

[6]Proteomic analysis of mycelial proteins from Magnaporthe oryzae under nitrogen starvation. Zhou, X. -G.,Zhao, Z. -W.,Zhou, X. -G.,Yu, P.,Dong, C.,Yao, C. -X.,Ding, Y. -M.,Tao, N.,Zhou, X. -G.,Yu, P.,Dong, C.,Yao, C. -X.,Ding, Y. -M.,Tao, N.. 2016

[7]Profiling of triacylglycerols in plant oils by high-performance liquid chromatography-atmosphere pressure chemical ionization mass spectrometry using a novel mixed-mode column. Hu, Na,Wei, Fang,Lv, Xin,Wu, Lin,Dong, Xu-Yan,Chen, Hong,Hu, Na,Wei, Fang,Lv, Xin,Wu, Lin,Dong, Xu-Yan,Chen, Hong. 2014

[8]Purification of a Novel Angiotensin I-Converting Enzyme (ACE) Inhibitory Peptide with an Antihypertensive Effect from Loach (Misgurnus anguillicaudatus). Li, Ying,Sun, Yi,Zeng, Xiaoxiong,Li, Ying,Zhou, Jianzhong,Huang, Kaihong. 2012

[9]Metabolite profiles of rice cultivars containing bacterial blight-resistant genes are distinctive from susceptible rice. Huang, Xin,Zhu, Shuifang,Wu, Jiao,Yu, Haichuan,Wu, Jiao,Dai, Haofu,Mei, Wenli,Peng, Ming. 2012

[10]Advances in ESI-MS/MS Approach-based Plant Lipidomics. Mei Xu-Rong. 2010

[11]Modulation of protein expression in alfalfa (&ITMedicago sativa&IT L.) root and leaf tissues by &ITFusarium proliferatum&IT. Cong Li-li,Long Rui-cai,Kang Jun-mei,Zhang Tie-jun,Wang Zhen,Yang Qing-chuan,Sun Yan,Li Ming-na,Cong Li-li. 2017

[12]Proteomic identification of differentially expressed proteins in Gossypium thurberi inoculated with cotton Verticillium dahliae. Zhao, Fu'an,Fang, Weiping,Xie, Deyi,Zhao, Yuanming,Tang, Zhongjie,Li, Wu,Nie, Lihong,Lv, Shuping,Zhao, Fu'an. 2012

[13]Proteomic Analysis of Proteins in the Salivary Glands of the Fed and Unfed Female Tick Rhipicephalus haemaphysaloides. Xiang Fei-yu,Zhang Jian-wu,Zhou Yong-zhi,Li Zhuang,Gong Hai-yan,Zhou Jin-lin,Xiang Fei-yu. 2009

[14]Proteomic analysis of liver development of lean Pekin duck (Anas platyrhynchos domestica). Zhang, Yunsheng,Hou, Shuisheng,Zheng, Aijuan,Liu, Guohua,Chang, Wenhuan,Zhang, Shu,Cai, Huiyi,Chen, Guilan.

[15]Metabolic changes of peanut (Arachis hypogaea L.) buds in response to low temperature (LT). Wang, X. J.,Sun, D. L.,Bian, N. F.,Zhang, Z. M.,Wang, X.,Xu, Z. J.,Qi, Y. J.,Shen, Y..

[16]Determination of the aflatoxin AFB1 from corn by direct analysis in real time-mass spectrometry (DART-MS). Busman, Mark,Bobell, John R.,Maragos, Chris M.,Liu, Jihong,Zhong, Hongjian. 2014

[17]Proteomics of methyl jasmonate induced defense response in maize leaves against Asian corn borer. Zhang, Yi Tong,Chen, Si Xue,Yang, Ze Zhong,Liu, Chun Guang,Zhao, Dan Dan,Ma, Yu Kun,Song, Fu Qiang,Yang, Feng Shan,Zhang, Yu Liang,Yin, Guo Hua,Zhang, Yi Tong,Chen, Si Xue,Yin, Guo Hua,Lee, Samantha,Bennett, Joan W.,Yang, Ze Zhong,Liu, Chun Guang,Zhao, Dan Dan,Ma, Yu Kun,Song, Fu Qiang,Yang, Feng Shan. 2015

[18]Comparative Proteomic Analysis of Yak Follicular Fluid during Estrus. Guo, Xian,Pei, Jie,Ding, Xuezhi,Chu, Min,Bao, Pengjia,Wu, Xiaoyun,Liang, Chunnian,Yan, Ping.

[19]Construction and functional characterization of truncated versions of recombinant keratanase II from Bacillus circulans. Wang, Haisheng,Wang, Haisheng,He, Wenqin,Koffas, Mattheos,Zhang, Fuming,Linhardt, Robert J.,Jiang, Peixia,Yu, Yanlei,Lin, Lei,Sun, Xiaojun,Linhardt, Robert J.,Jiang, Peixia,Linhardt, Robert J.,Linhardt, Robert J..

[20]Analysis of flavonoids from lotus (Nelumbo nucifera) leaves using high performance liquid chromatography/photodiode array detector tandem electrospray ionization mass spectrometry and an extraction method optimized by orthogonal design. Chen, Sha,Liu, Yan-Ling,Fang, Lin-Chuan,Li, Shao-Hua,Chen, Sha,Wu, Ben-Hong,Zhang, Hao-Hao,Guan, Le,Chen, Sha,Fang, Jin-Bao.

作者其他论文 更多>>