Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

文献类型: 外文期刊

第一作者: Ma Zheng

作者: Ma Zheng;Dong Xiaoxia;Zhang Bosong;Xu Changying;Hu Yufeng;Liu Yansheng

作者机构:

关键词: ionic liquid;activity coefficients at infinite dilution;organic reactions

期刊名称:CHINESE JOURNAL OF CHEMICAL ENGINEERING ( 影响因子:3.171; 五年影响因子:2.853 )

ISSN: 1004-9541

年卷期: 2013 年 21 卷 12 期

页码:

收录情况: SCI

摘要: It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

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