Synthesis, Structure and Mechanism of a Lithium Complex with Hexanuclear Cage Structure

文献类型: 外文期刊

第一作者: Wang Li

作者: Wang Li;Xue Xiao-Yan;Huang Shu-Ping;Chen Xia;Chen Xia;Chang Gong-Min

作者机构:

关键词: synthesis;structure;lithium complex;mechanism

期刊名称:CHINESE JOURNAL OF INORGANIC CHEMISTRY ( 影响因子:0.834; 五年影响因子:0.604 )

ISSN: 1001-4861

年卷期: 2011 年 27 卷 5 期

页码:

收录情况: SCI

摘要: A novel hexanuclear cage lithium complex 3 was synthesized by addition reaction of [PhN(SiMe(2)(OMe))Li](2) with piperidyl nitrite and its crystal structure was determined. Compound 3 was characterized by (1)H NMR spectra and X-ray diffraction patterns. The crystal of compound 3 shows a cage structure and belongs to monoclinic space group: P2(1)/n, with a=1.248 83(19) nm, b=1.402 7(2) nm, c=1.853 4(3) nm; beta=95.894(2)degrees; V=3229.5(8) nm(3), Z=2, R(1)=0.047 7, GOF=0.946. CCDC: 816546.

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