NMR Analysis of Polysaccharide ASP3 from Angelica sinensis (Oliv.) Diels and It's Hydrolysis Products

文献类型： 外文期刊

第一作者： Sun Yuan-Lin

作者： Sun Yuan-Lin;Shan Fang;Cui Wu-Wei;Tang Jian;Gu Xiao-Hong

作者机构：

关键词： Angelica sinensis;Pectic polysaccharide;Partial acid hydrolysis;Enzymic digestion;NMR

期刊名称：CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE （ 影响因子：0.65； 五年影响因子：0.481 ）

ISSN： 0251-0790

年卷期： 2009 年 30 卷 9 期

页码：

收录情况： SCI

摘要： The structural features of polysaccharide ASP3 were studied. ASP3 was hydrolyzed with 0.2 mol/L trifluoroacetic acid and was enzymic hydrolyzed with endo-alpha-(1 -> 4)-polygalacturonases. NMR analysis method was conducted on the samples. The results indicated that ASP3 was a kind of pectic polysaccharide which contained the main part of homogalacturonan fragments as "smooth regions" with alpha-(1 -> 4)-GalpA, ant rhamnogalacturonan segments as "hairy regions" backbone. Gal and Ara, which were the mainly constitution of the branch, substituted at O4 position of Rhap residues in the backbone. Man and Glc were linked as arabinogalactan, galactan and arabinan. Terminal, beta-(1 -> 3)-, beta-(1 -> 3, 6)-, beta-(1 -> 4)-, and beta-(1 -> 4, 6)-Galp as well as residues of terminal, alpha-(1 -> 5)-, and alpha-(1 -> 3, 5)-Araf were linked to forth beta-(1 -> 6)- or beta-(1 -> 4)-galactans bearing 3, 6- or 4,6-substituted beta-Galp residues as branched points respectively, and short alpha-(1 -> 5)-arabinan possessing 3, 5-substituted alpha-Ara residues as branched points. In addition, arabinogalactan was found to contain branched sugar chains of alpha-(1 -> 5)-arabinan attached to the linear chains of beta-(1 -> 6)-galactan by 1,3-linkages.

分类号：

  • 相关文献

[1]Structure of oligosaccharide F21 derived from exopolysaccharide WL-26 produced by Sphingomonas sp ATCC 31555. Jia, Wei,Jiang, Yun,Zheng, Zhi-Yong,Zhan, Xiao-Bei,Lin, Chi-Chung,Zhang, Jin-Song. 2012

[2]Partial Acid Hydrolytic Characteristics and Methylation Analysis of Pentosans from Black-grained Wheat Bran. Sun Yuan-Lin,Zhang Jun-Ming,Gu Xiao-Hong,Shan Fang,Cui Wu-Wei. 2012

[3]Multivariate Analysis of Trace Element Contents in Angelica sinensis and Soil. Jin, Hang,Wang, Yuanzhong,Zhao, Zhenling,Yang, Weize,Yang, Meiquan,Zhang, Ji,Zhang, Jinyu,Zhang, Jinyu. 2011

[4]Hepatoprotective and antioxidant effects of dietary Angelica sinensis extract against carbon tetrachloride-induced hepatic injury in Jian Carp (Cyprinus carpio var. Jian). Cao, Liping,Du, Jinliang,Ding, Weidong,Xu, Pao,Yin, Guojun,Cao, Liping,Du, Jinliang,Liu, Yingjuan,Xu, Pao,Yin, Guojun,Jia, Rui,Liu, Yingjuan,Teraoka, Hiroki.

[5]Structural Characterisation Of A Heteropolysaccharide By Nmr Spectra. Ye, LiBin,Zhang, JingSong,Yang, Yan,Zhou, Shuai,Liu, YanFang,Tang, Qinglui,Du, Xiuju,Chen, Hui,Ye, LiBin,Du, Xiuju,Pan, YingJie.

[6]Comprehensive separation and identification of chemical constituents from Apocynum venetum leaves by high-performance counter-current chromatography and high performance liquid chromatography coupled with mass spectrometry. Zhang, Yuchi,Liu, Chunming,Wang, Jing,Wu, Guimei,Li, Sainan,Zhang, Zhengkun.

[7]Toxoplasma gondii immune mapped protein 1 is anchored to the inner leaflet of the plasma membrane and adopts a novel protein fold. Jia, Yonggen,Dogga, Sunil Kumar,Soldati-Favre, Dominique,Benjamin, Stefi,Xu, Yingqi,Matthews, Stephen,Liu, Qun,Liu, Jing.

[8]23,24-Dihydrocucurbitacin C: A new compound regarded as the next metabolite of cucurbitacin C. Qing, Zhi-Xing,Zeng, Jian-Guo,Zhou, Yuan,Liu, Xiu-Bin,Cheng, Pi,Zeng, Jian-Guo.

[9]Freeze drying and vacuum impregnating characteristics of Nostoc sphaeroides Kutzing. Lv, Weiqiao,Zhang, Min,Wang, Yuchuan,Zhang, Min,Bhandari, Bhesh,Liu, Chunquan.

[10]Geographical Origin Discrimination of Oolong Tea (TieGuanYin, Camellia sinensis (L.) O. Kuntze) Using Proton Nuclear Magnetic Resonance Spectroscopy and Near-Infrared Spectroscopy. Meng, Weijun,Xu, Xiangnan,Xu, Jingjing,Shen, Guiping,Dong, Jiyang,Cheng, Kian-Kai,Wu, Zhidan.

[11]Two new monascus red pigments produced by Shandong Zhonghui Food Company in China. Lian, Xijun,Dong, Shirui,Liu, Lizeng,Wu, Hong,Zhao, Jixing,Han, Yanjun.

[12]Retrograded maize starch used as a medium to enrich Monascus from the air in winter. Liu, Lizeng,Wang, Danli,Lian, Xijun,Wu, Hong.

[13]Structural studies of the exopolysaccharide from Lactobacillus plantarum C88 using NMR spectroscopy and the program CASPER. Fontana, Carolina,Widmalm, Goran,Li, Shengyu,Yang, Zhennai.

[14]Identification of new trace triterpenoids from the fungus Ganoderma duripora. Lian, Chenlei,Wu, Yaqing,Liu, Xuqiang,Cong, Hui,Xiao, Lei,Xu, Ying,Liu, Jieqing,Wu, Yaqing,Liu, Jieqing,Chen, Tiqiang. 2017

[15]Effects of temperature on soil organic carbon fractions contents, aggregate stability and structural characteristics of humic substances in a Mollisol. Gao, Shuqing,Li, Cuilan,Zhang, Jinjing,Wang, Lichun. 2016

[16]Structural elucidation and antioxidant activity of a novel polysaccharide (TAPB1) from Tremella aurantialba. Du, Xiuju,Zhang, Yang,Lv, Zhiwei,Yang, Yan,Zhang, Jingsong,Mu, Hongmei.

[17]Complete H-1-NMR and C-13-NMR spectral assignment of five malonyl ginsenosides from the fresh flower buds of Panax ginseng. Wang, Yu-Shuai,Jin, Yin-Ping,Gao, Wei,Xiao, Sheng-Yuan,Zhang, Yu-Wei,Zheng, Pei-He,Wang, Jia,Liu, Jun-Xia,Sun, Cheng-He,Wang, Ying-Ping,Xiao, Sheng-Yuan. 2016

[18]Synthesis and spectral analysis of 12H-dibenzo[1,3,2]dioxaphosphocins. Chen, WY,Li, CJ. 2003

[19]Pullulan production from synthetic medium by a new mutant of Aureobasidium pullulans. Chen, Guoqiang,Wang, Jiming,Zhang, Ge,Zhao, Hongwei,Yang, Ying,Nian, Rui,Zhang, Haibo,Xian, Mo,Chen, Guoqiang,Wei, Yuxi,Su, Yulong,Zhang, Ge,Liu, Haobao,Zhu, Youshuang. 2017

[20]Purification, NMR Study and Immunostimulating Property of a Fucogalactan from the Fruiting Bodies of Ganoderma lucidum. Ye, Libin,Zhang, JingSong,Yang, Yan,Zhou, Shuai,Jia, Wei,Hao, RuiXia,Ye, Libin,Zhou, Kan,Pan, Yinglie. 2008

作者其他论文 更多>>

微信小程序