Synthesis, characterization and acidochromism of Poly (2-N,N-dimethylamino-4,6-Bis (2-thienyl)-pyrimidine)

文献类型： 外文期刊

第一作者： Mamtimin, Xirali

作者： Mamtimin, Xirali;Aikebaierjiang, Aierken;Alifujiang, Musitake;Nurulla, Ismayil;Mamtimin, Xirali;Nurulla, Ismayil;Tuerxun, Tuerhong;Kurban, Zaytungul;Sun, Wan Fu

作者机构：

关键词： Polymer;Optical properties;Acidochromism

期刊名称：JOURNAL OF POLYMER RESEARCH （ 影响因子：3.097； 五年影响因子：2.599 ）

ISSN： 1022-9760

年卷期： 2011 年 18 卷 1 期

页码：

收录情况： SCI

摘要： A new monomer (2-N,N-dimethylamino-4,6-Bis (2-thienyl)-pyrimidine) was synthesized and its homopolymer was successfully prepared by using Ferric trichloride (FeCl(3)) as an oxidant. The structure of the polymer and monomer was fully characterized by (1)H-NMR, FTIR, UV-vis, Fluorescent spectroscopy and X-ray diffraction pattern. The polymer gives rise to a band at lambda (max) = 391 nm. The polymer showed the PL spectrum, gave a peak at 507 nm.We have observed that the polymer was sensitive to inorganic acids and the acidochromism behavior was investigated applying organic acid such as CF(3)COOH. The corresponding UV-Vis peaks were observed at 464 nm and 357 nm respectively. X-ray diffraction data shows that polymer has a certain crystallinity. The polymer exhibited an [eta] value of 0.26 dLg(-1) at 25 A degrees C in H(2)SO(4) (w = 98%).

分类号：

  • 相关文献

[1]Synthesis, Characterization, and Protonation of Poly(2-N,N-dimethylamino-4,6-bis(2-furan)-pyrimidine). Mamtimin, Xirali,Aikebaierjiang, Aierken,Rukeyamu, Maitisidike,Alifujiang, Musitake,Nurulla, Ismayil,Tuerxun, Tuerhong,Kurban, Zaytungul,Sun, Wan Fu. 2010

[2]Study on an antifouling and blood compatible poly(ethylene-vinyl acetate) material with fluorinated surface structure. Wen, Xiao-Wen,Pei, Su-Peng,Li, Hong,Ai, Fei,Chen, Huan,Zhang, Yong-Ming,Li, Ke-Yong,Wang, Quan.

[3]Fluorescence enhancement thermoresponsive polymer luminescent sensors based on BODIPY for intracellular temperature. Gong, Deyan,Cao, Ting,Iqbal, Anam,Liu, Weisheng,Qin, Wenwu,Gong, Deyan,Cao, Ting,Iqbal, Anam,Liu, Weisheng,Qin, Wenwu,Han, Shi-Chong,Zhu, Xiangtao,Guo, Huichen,Han, Shi-Chong,Zhu, Xiangtao,Guo, Huichen.

[4]Characterization of GTMAC-Graft-Chitosan as a Bactericidal Agent for Nitric Oxide Release. Sun, Yan,Yang, Peng,Liu, Yong,Xu, Yaoxing,Li, Yanli,Xu, Shaochun. 2011

[5]Luminescent and thermal properties of a novel red-emitting silicon fluoride acrylate-Eu(III) copolymer for white LEDs. Hu, Jun,Xu, Lin,Xie, Hongde,Xu, Lei,Tsuboi, Taiju,Huang, Wei,Tsuboi, Taiju,Huang, Wei. 2014

[6]A SIMPLE ROUTE TO CONTROLLABLY SYNTHESIZE WATER-SOLUBLE ZNCDTE NANORODS AND NANOPARTICLES. Wang Yan,Cui Hai-Xin,Sun Chang-Jiao,Hou Yan-Bing,Lu Yun-Zhang. 2011

[7]Synthesis and characterization of fluorene-based rod-coil liquid crystal polymers. Chen, Xiao-Lei,Wang, Lu-Min,Shi, Jian-Gao,Yang, Gui-Zhong,Liu, Tianxi,Li, Chun-Zhong.

作者其他论文 更多>>

微信小程序