Mechanism and Effective Factors of Acyl Migration of Lysophospholipid

文献类型: 外文期刊

第一作者: Zhang Kangyi

作者: Zhang Kangyi;Qu Lingbo;Zhang Kangyi;Zhang Lixia;Wang Xingguo;Liu Yuanfa

作者机构:

关键词: lysophospholipid;acyl migration;mechanism;effective factors

期刊名称:CHINESE JOURNAL OF ORGANIC CHEMISTRY ( 影响因子:1.652; 五年影响因子:1.2 )

ISSN: 0253-2786

年卷期: 2014 年 34 卷 12 期

页码:

收录情况: SCI

摘要: The specificity hydrolysis Sn-1 fatty acyl of phospholipids by phospholipase A(1) and the phenomenon of acyl migration in Sn-2-lysophosphatidylcholine (Sn-2-LPC) were demonstrated through C-13 NMR, which provided fundamental basis for enzymatic reaction solution of phosphatidylcholine (PC) including Sn-1-lysophosphatidylcholine, Sn-2-LPC, and L-alpha-glycerylphosphorylcholine. Based on the automatic acyl migration mechanism of monoglycerides,,the automatic acyl, migration mechanism of Sn-2-LPC was speculated in the acid condition or alkali condition. The effects of reaction parameters on the acyl migration were then explored, including the polarity of the solution, pH, temperature, substrate concentration, and reaction time. The conditions of low acyl migration were as follows: isopropanol solvent, pH 7 similar to 8, temperature<35 degrees C, defined substrate concentration, shorten reaction time. These results contributed to a data support for the synthesis of acyl mixture of phospholipids, detection of specific phospholipase A(1), and the explanation of biosynthetic pathway (lysophospholipid intermediate) of the production mixed phospholipid.

分类号:

  • 相关文献

[1]Genotypic Variation in Wheat Flour Lysophospholipids. Liu, Lei,Guo, Qi,Waters, Daniel L. E.,Raymond, Carolyn A.,King, Graham J.,Guo, Qi,He, Zhonghu,Xia, Xianchun,He, Zhonghu.

[2]Ultrasonic pretreatment in lipase-catalyzed synthesis of structured lipids with high 1,3-dioleoyl-2-palmitoylglycerol content. Liu, Si-lei,Dong, Xu-yan,Wei, Fang,Wang, Xiang,Lv, Xin,Zhong, Juan,Wu, Lin,Chen, Hong,Quek, Siew-young.

[3]Structures of the Ozonolysis Products and Ozonolysis Pathway of Aflatoxin B-1 in Acetonitrile Solution. Diao, Enjie,Shan, Changpo,Hou, Hanxue,Dong, Haizhou,Wang, Shanshan,Li, Minghua. 2012

[4]The Mechanism by Which Dodecyl Dimethyl Benzyl Ammonium Chloride Increased the Toxicity of Chlorpyrifos to Spodoptera exigua. Cui, Li,Yuan, Huizhu,Yang, Daibin,Rui, Changhui,Mu, Wei. 2017

[5]Advances in characterisation and biological activities of chitosan and chitosan oligosaccharides. Zou, Pan,Yang, Xin,Wang, Jing,Zhang, Yanxin,Liu, Guangyang,Zou, Pan,Yang, Xin,Wang, Jing,Li, Yongfei,Yu, Hailong,Zhang, Yanxin,Liu, Guangyang,Wang, Jing,Li, Yongfei,Yu, Hailong. 2016

[6]Potential use of anaerobically digested manure slurry to suppress Phytophthora root rot of chilli pepper. Cao, Yun,Chang, Zhizhou,Wang, Jidong,Ma, Yan,Yang, Hao,Fu, Guangqin. 2014

[7]In vitro Antimicrobial Activities and Mechanism of 1-Octen-3-ol against Food-related Bacteria and Pathogenic Fungi. Li, Qiang,Chen, Zuqin,Xiong, Chuan,Li, Qiang,Huang, Wenli,Li, Shuhong,Chen, Cheng. 2017

[8]Chlorination of parabens: reaction kinetics and transformation product identification. Mao, Qianhui,Wang, Wei,Hu, Zhenhu,Yuan, Shoujun,Ji, Feng,Wang, Qiquan,Yuan, Shoujun. 2016

[9]Synthesis, Structure and Mechanism of a Lithium Complex with Hexanuclear Cage Structure. Wang Li,Xue Xiao-Yan,Huang Shu-Ping,Chen Xia,Chen Xia,Chang Gong-Min. 2011

[10]Molecular and biochemical characterization of a distinct tyrosinase involved in melanin production from Aeromonas media. Wan, Xia,Chai, Baozhong,Liao, Yi,Ye, Tao,Shen, Ping,Chen, Xiangdong,Wan, Xia,Su, Ying.

[11]Rab3A is a new interacting partner of synaptotagmin I and may modulate synaptic membrane fusion through a competitive mechanism. Xie, Chunliang,Li, Jianglin,Guo, Tianyao,Yan, Yizhong,Tang, Cheng,Wang, Ying,Chen, Ping,Wang, Xianchun,Liang, Songping,Xie, Chunliang.

[12]Quantitative structure-toxicity relationship study of lethal concentration to tadpole (Bufo vulgaris formosus) for organophosphorous pesticides. Yan, Dongyun,Xu, Shaohui,Yan, Dongyun,Jiang, Xin,Bian, Yongrong,Yu, Guifen,Wang, Ligang.

[13]Study on the cationic modification and dyeing of ramie fiber. Liu, Zhao-Tie,Yang, Yani,Zhang, Lili,Liu, Zhong-Wen,Xiong, Heping.

[14]Combined Systems Approaches Reveal a Multistage Mode of Action of a Marine Antimicrobial Peptide against Pathogenic Escherichia coli and Its Protective Effect against Bacterial Peritonitis and Endotoxemia. Wang, Xiumin,Teng, Da,Mao, Ruoyu,Yang, Na,Hao, Ya,Wang, Jianhua,Wang, Xiumin,Teng, Da,Mao, Ruoyu,Yang, Na,Hao, Ya,Wang, Jianhua.

[15]Engineered Bacillus thuringiensis GO33A with broad insecticidal activity against lepidopteran and coleopteran pests. Wang, Guangjun,Zhang, Jie,Song, Fuping,Wu, Jun,Feng, Shuliang,Huang, Dafang.

[16]Investigation on High Performance of Graphite-Ionic Liquid Paste Electrode: Characterization and New Hypothesis. Zhang, Xuzhi,Cui, Yi,Zhu, Jianxin,Zhao, Jun,Chen, Bijuan,Qu, Keming,Li, Meng. 2013

[17]Extraction of phytochemicals using hydrotropic solvents. Heng, Wong Wah,Ramanan, Ramakrishnan Nagasundara,Beng-Ti, Tey,Prasad, Krishnamurthy Nagendra,Galanakis, Charis M.,Raghunandan, Mavinakere Eshwaraiah,Sun, Jian,Ismail, Amin. 2016

[18]Purification and Characterisation of a Fungicidal Peptide from Bacillus amyloliquefaciens NCPSJ7. Wang, Junhua,Zhao, Shuangzhi,Qiu, Jiying,Zhou, Qingxin,Liu, Xiaoyong,Xin, Xue,Wang, Yifen,Sun, Hua,Chen, Xiangyan,Chen, Leilei,Wang, Junhua,Zhao, Shuangzhi,Qiu, Jiying,Zhou, Qingxin,Liu, Xiaoyong,Xin, Xue,Wang, Yifen,Sun, Hua,Chen, Xiangyan,Chen, Leilei,Guo, Danyang,Yudina, Tatyana G..

[19]Analysis of differentially expressed proteins in zebrafish (Danio rerio) embryos exposed to chlorpyrifos. Liu, Lili,Xu, Yongxue,Xu, Lili,Wang, Jian,Wu, Wei,Xu, Lei,Yan, Yanchun,Xu, Yongxue. 2015

[20]Accumulating mechanism of -aminobutyric acid in soybean (Glycine max L.) during germination. Luo, Xu,Wang, Yan,Li, Qianqian,Wang, Donghui,Xing, Cencan,Zhang, Lijing,Xu, Teng,Fang, Fang,Wang, Fengzhong. 2018

作者其他论文 更多>>