Structure and Properties of Self-assembled Narural Rubber/Multi-walled Carbon Nanotube Composites

文献类型: 外文期刊

第一作者: Peng Zheng

作者: Peng Zheng;Luo Yongyue;Feng Chunfang;Yi Zhifeng;Kong Lingxue

作者机构:

关键词: natural rubber (NR);multi-walled carbon nanotube (MWCNTs);composites;latex compounding;self-assembly

期刊名称:JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION ( 影响因子:0.957; 五年影响因子:0.959 )

ISSN: 1000-2413

年卷期: 2011 年 26 卷 5 期

页码:

收录情况: SCI

摘要: Natural rubber (NR)/multi-walled carbon nanotube (MWCNTs) composites were prepared by combining self-assembly and latex compounding techniques. The acid-treated MWCNTs (H(2)SO(4): HNO(3)=3:1, volume ratio) were self-assembled with poly (diallyldimethylammonium chloride) (PDDA) through electrostatic adhesion. In the second assembling, NR/MWCNTs composites were developed by mixing MWCNTs/PDDA solution with NR latex. The results show that MWCNTs arc homogenously distributed throughout the NR matrix as single tube and present a great interfacial adhesion with NR phase when MWCNTs contents are less than 3 wt%. Moreover, the addition of the MWCNTs brings about the remarkable enhancement in tensile strength and crosslink density compared with the NR host, and the data peak at 2 wt% MWCNTs loadings. When more MWCNTs are loaded, aggregations of MWCNTs are gradually generated, and the tensile strength and crosslink both decrease to a certain extent.

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