Petaloid MoS2@MIL-88B(Fe) nanocomposite photocatalyst utilized to achieve accurate SWASV detection of Cd2+and Pb2+in water under low-pressure ultraviolet irradiation
文献类型： 外文期刊
作者： He, Renjie 1 ; Feng, Liya 1 ; Chen, Shaowen 2 ; Zhang, Shijie 2 ; Shi, Yujie 2 ; Liu, Ning 3 ; Liu, Gang 3 ; Zhao, Xiande 3 ; Zhao, Guo 2 ;
作者机构： 1.Nanjing Agr Univ, Coll Engn, Nanjing 210031, Peoples R China
2.Nanjing Agr Univ, Coll Artificial Intelligence, Nanjing 210031, Peoples R China
3.China Agr Univ, Key Lab Modern Precis Agr Syst Integrat Res, Minist Educ China, Beijing 100083, Peoples R China
4.Beijing Acad Agr & Forestry Sci, Res Ctr Intelligent Equipment, Beijing 100097, Peoples R China
关键词： Heavy metal detection; Humic acid interference; Pretreatment method; SWASV; MoS2@MIL-88B(Fe) nanocomposite
期刊名称：ENVIRONMENTAL TECHNOLOGY & INNOVATION （ 影响因子：7.1； 五年影响因子：7.1 ）
ISSN： 2352-1864
年卷期： 2025 年 38 卷
页码：
收录情况： SCI
摘要： Humic acid (HA) is an organic compound in natural water and can be complexed with heavy metal ions (HMIs), which interferes with the detection of square wave anodic stripping voltammetry (SWASV). In this study, a petaloid MoS2@MIL-88B(Fe) nanocomposite was synthesized via hydrothermal synthesis. Leveraging its ability to generate active species under low-pressure ultraviolet (LPUV) irradiation, a MoS2@MIL-88B(Fe)/LPUV-based pretreatment method was proposed to detect HMIs in water by disrupting the complexation between HA and HMIs, thus restoring the SWASV signals of HMIs. The microstructure, crystal structure, surface chemical state, band gap, photogenerated charge separation and recombination rates of MoS2@MIL-88B (Fe) were investigated, along with the degradation kinetics of HA, byproducts, and active species generated during pretreatment, to elucidate both the mechanism behind the disruption of HA- HMIs complexation and the restoration of SWASV signals. Additionally, the key pretreatment parameters, such as pH, the MoS2 to MIL-88B(Fe) mass ratio, the photocatalyst concentration, and the photolysis time, were optimized for the choice signal restoration ratio. The proposed MoS2@MIL-88B(Fe)/LPUV-based pretreatment method was applied to real water samples, yielding a root mean square error (RMSE) of less than 0.2 mu g/L compared with that of the national standard method, confirming its authenticity and feasibility.
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