文献类型： 外文期刊
作者： Zhi, Yue 1 ; Shao, Jiawei 1 ; Liu, Chen 1 ; Xiao, Qiang 2 ; Demir, Muslum 3 ; Al Mesfer, Mohammed K. 5 ; Danish, Mohd 5 ; Wang, Linlin 6 ; Hu, Xin 1 ;
作者机构： 1.Zhejiang Normal Univ, Key Lab Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China
2.Beijing Acad Agr & Forestry Sci, Inst Plant Nutr Resources & Environm, Beijing 100097, Peoples R China
3.Bogaz Univ, Dept Chem Engn, TR-34342 Istanbul, Turkiye
4.TUBITAK Marmara Res Ctr, Mat Inst, TR-41470 Gebze, Turkiye
5.King Khalid Univ, Coll Engn, Chem Engn Dept, K S & Cent Labs, Abha 61413, Saudi Arabia
6.Zhejiang Normal Univ, Coll Engn, Key Lab Urban Rail Transit Intelligent Operat & Ma, Jinhua 321004, Zhejiang, Peoples R China
关键词： P-doped porous carbons; CO2 adsorption; KOH activation; Phytic acid; Biomass
期刊名称：SEPARATION AND PURIFICATION TECHNOLOGY （ 影响因子：9.0； 五年影响因子：8.5 ）
ISSN： 1383-5866
年卷期： 2025 年 361 卷
页码：
收录情况： SCI
摘要： Combating climate change and global warming generally involves reducing CO2 level from the air. To achieve this, in present study, phosphorus-doped porous carbons were prepared using biomass lotus petiole as the precursor. The synthesis procedure involves first pre-carbonization of lotus petiole at elevated temperature and secondly, introducing phosphorus atoms by phytic acid modification, which then chemically activated at various temperature and amount of KOH. Resulting carbons present advanced textural feature (the BET surface area of up to 1456 m2/g along with 0.68 cm3/g of pore volume) and high amount of P doping (up to 3.39 wt%). These Pdoped adsorbent have exhibited excellent CO2 capture capacity, achieving 4.00 mmol/g at 25 degrees C and 6.05 mmol/ g at 0 degrees C at about 1 bar pressure. Additionally, these adsorbents demonstrated practical stability for maintaining over 97 % adsorption capacity after 5 sequential cycles as well as high CO2/N2 selecivity, moderate heat of adsorption, fast adsorption kinetics and good dynamic CO2 capture capacity from contineous flowing gas mixture. Thus, based on the superior CO2 capture performance of the as-prepared adsorbents, a new method of converting biomass into higly functional carbon materials is proposed for the field of carbon neutrality.
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