Polar semiconductor photocatalysts with intrinsic electric fields for selective organic transformation
文献类型： 外文期刊
作者： Huang, Mianli 1 ; Yu, Maoqing 1 ; Si, Ruiru 2 ; Xu, Wentao 1 ; Xu, Miaoqiong 1 ; Xiao, Chunmei 1 ; Chen, Wen-Jie 1 ; Sun, Lidan 1 ; Weng, Bo 3 ; Pan, Xiaoyang 1 ;
作者机构： 1.Quanzhou Normal Univ, Coll Chem Engn & Mat, Quanzhou 362000, Peoples R China
2.Fujian Acad Agr Sci, Inst Qual Stand & Testing Technol Agroprod, Fujian Key Lab Agroprod Qual & Safety, Fuzhou 350003, Peoples R China
3.Katholieke Univ Leuven, Dept Microbial & Mol Syst, MACS, Celestijnenlaan 200F, B-3001 Leuven, Belgium
期刊名称：NEW JOURNAL OF CHEMISTRY （ 影响因子：3.925； 五年影响因子：3.629 ）
ISSN： 1144-0546
年卷期： 2023 年 47 卷 2 期
页码：
收录情况： SCI
摘要： Semiconductor photocatalysts have been widely investigated in the field of selective organic transformation. However, the practical application of photocatalysts is greatly limited due to their low charge separation efficiency. Recently, electron-hole separation using intrinsic electric field of polar semiconductors has attracted much attention. Polarity exists widely in polar noncentrosymmetric (NCS) materials, such as piezoelectric, pyroelectric and ferroelectric materials. In the crystal structure of NCS materials, the asymmetric arrangement of ions or ion groups leads to the distribution of positive and negative charges on the surface in opposite directions, which could effectively separate the electron-hole pairs. This perspective summarized recent progress in the synthesis and photocatalytic application of polar semiconductors for selective organic synthesis. This paper also briefly introduces the working mechanism of a light free or vibration catalyst (piezoelectric catalyst). Generally, this perspective mainly focuses on five kinds of polar semiconductors, including CdS, ZnO, ABO(3), bismuth layered materials and two-dimensional polar materials. The challenges encountered, as well as the current and future scopes of this field are also discussed in this perspective.
- 相关文献
作者其他论文 更多>>
-
Strain-Induced Photocatalytic H2 Production over BiVO4 in Pure Water without Any Cocatalyst
作者：Lu, Xiaoxiao;Wang, Xiangge;Zheng, Shifan;Zhao, Xiaojing;Xu, Wentao;Pan, Xiaoyang;Si, Ruiru;Yi, Zhiguo
关键词：
-
Characterization, stability and antioxidant activity of curcumin nanocomplexes with soy protein isolate and pectin
作者：Fu, Lijuan;Tan, Suo;Si, Ruiru;Qiang, Yueyue;Wei, Hang;Huang, Biao;Shi, Mengzhu;Fang, Ling;Fu, Jianwei;Qiang, Yueyue;Fu, Jianwei;Zeng, Shaoxiao;Fu, Jianwei
关键词：Curcumin; Soy protein isolate; Pectin; Nanocomplexes; Antioxidant activity
-
Tailoring Morphology in Hydrothermally Synthesized CdS/ZnS Nanocomposites for Extraordinary Photocatalytic H-2 Generation via Type-II Heterojunction
作者：Huang, Mianli;Yu, Maoqing;Zhao, Xiaojing;Chen, Shuqin;Liu, Kewei;Pan, Xiaoyang;Si, Ruiru
关键词：photocatalyst; chemical state; core shell; H-2 production
-
Microemulsion-Assisted Synthesis of Ag2CrO4@MIL-125(Ti)-NH2 Z-Scheme Heterojunction for Visible-Light Photocatalytic Inactivation of Bacteria
作者：Yuan, Haoyu;Zhang, Chao;Liang, Ruowen;Yuan, Haoyu;Zhang, Chao;Chen, Wenjing;Xia, Yuzhou;Chen, Lu;Huang, Renkun;Liang, Ruowen;Si, Ruiru
关键词：MIL-125(Ti)-NH2; Ag2CrO4; S. aureus; Z-scheme; microemulsion method
-
Amino-functionalized MIL-125(Ti) for photodenitrification of pyridine in fuels via coordination activation by unsaturated Ti4+ centers
作者：Wang, Shihui;He, Zhoujun;Wang, Deling;Liang, Ruowen;Wang, Shihui;He, Zhoujun;Wang, Deling;Liu, Xiyao;Liang, Ruowen;Wang, Shihui;Wu, Ling;Wang, Deling;Liang, Ruowen;Si, Ruiru
关键词：
-
Formation of CdS quantum dots on zeolitic imidazolate framework-67 dodecahedrons as S-scheme heterojunctions to enhance charge separation and antibacterial activity
作者：Liang, Ruowen;Yuan, Haoyu;Wang, Shihui;Chen, Feng;Yan, Guiyang;Liang, Ruowen;Yuan, Haoyu;Wang, Shihui;Wu, Ling;Yan, Guiyang;Si, Ruiru;Yan, Guiyang
关键词：Zeolitic imidazolate framework-67; CdS quantum dots; Step -scheme; Photocatalysis; Staphylococcus aureus
-
Spatial variation of volatile organic compounds and antioxidant activity of turmeric (Curcuma longa L.) essential oils harvested from four provinces of China
作者：Qiang, Yueyue;Si, Ruiru;Tan, Suo;Wei, Hang;Huang, Biao;Wu, Miaohong;Shi, Mengzhu;Fang, Ling;Fu, Jianwei;Qiang, Yueyue;Tan, Suo;Fu, Jianwei;Zeng, Shaoxiao;Wu, Miaohong
关键词：Turmeric essential oils (TEOs); HS-SPME-GC-MS; Antioxidant activity; DPPH; Curcuma longa L
