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Simultaneous determination of 114 pesticides in complex Chinese herbal medicine Fritillaria using ordered mesoporous carbon CMK-3 as a reversed-dispersive solid phase extraction sorbent

文献类型： 外文期刊

作者： Wu, Tong 1 ; Qi, Peipei 2 ; Wang, Jiao 2 ; Wang, Zhiwei 2 ; Di, Shanshan 2 ; Xu, Hao 2 ; Zhao, Huiyu 2 ; Zhao, Changshan; 1 ;

作者机构： 1.Northeast Agr Univ, Coll Agr, 600 Changjiang Rd, Harbin 150030, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Qual & Stand Agroprod, State Key Lab Managing Biot & Chem Threats Qual &, Hangzhou 310021, Peoples R China

3.Agr Minist, Key Lab Pesticide Residue Detect, Hangzhou 310021, Peoples R China

4.Key Lab Detect Pesticide Residue & Control Zhejia, Hangzhou 310021, Peoples R China

期刊名称：RSC ADVANCES （ 影响因子：3.361； 五年影响因子：3.39 ）

ISSN：

年卷期： 2021 年 11 卷 7 期

页码：

收录情况： SCI

摘要： Fritillaria, a traditional Chinese herbal medicine, is classified into many medicinal species and contains numerous complex components. It is thus difficult to simultaneously detect multiple pesticide residues in different Fritillaria species. An easy, reliable, and widely applicable analytical method based on a modified Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method coupled with LC-MS/MS was developed to solve these problems encountered during pesticide residue analysis in complex Fritillaria matrices. Ordered mesoporous carbon CMK-3 and a primary secondary amine (PSA) were used as efficient purification sorbents by optimization of the QuEChERS process. Systematic method validation was performed for four species of Fritillaria. The matrix effect of pesticides varied among different Fritillaria species, and matrix-matched standard solutions were thus employed for quantitative analysis. The mean recoveries of all pesticides ranged from 88.6% to 95.5%, with mean relative standard deviations (RSD) lower than 6% at spiked concentrations of 30, 120, and 240 mu g kg(-1). The limits of quantification (LOQ) for the developed method were in the range of 30-120 mu g kg(-1). This method was further used to analyze 47 Fritillaria samples from Zhejiang province, China, and seven pesticides were detected in 22 Fritillaria samples. These results demonstrate that the developed method is suitable for an accurate analysis of multiple pesticide residues in various Fritillaria.

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