Synthesis of a novel biocomposite of poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) reinforced with acetylated cellulose nanocrystals
文献类型： 外文期刊
作者： Li, Dongna 1 ; Zhou, Jiao 1 ; Ma, Xiaojun 1 ; Li, Jianing 2 ;
作者机构： 1.Tianjin Univ Sci & Technol, Coll Packaging & Printing Engn, Tianjin 300222, Peoples R China
2.Chinese Acad Trop Agr Sci, RubberRes Inst, Danzhou 571737, Peoples R China
关键词： Poly (3-hydroxybutyrate-co-3-hydroxyhexanoate); Acetylated cellulose nanocrystals; Mechanical properties; Barrier properties
期刊名称：CELLULOSE （ 影响因子：5.044； 五年影响因子：5.271 ）
ISSN： 0969-0239
年卷期： 2019 年 26 卷 16 期
页码：
收录情况： SCI
摘要： A novel biocomposite of poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH)/acetylated cellulose nanocrystals (ACN/PHBH) was prepared by solution-casting after surface modification of cellulose nanocrystals (CNCs). Acetylated cellulose nanocrystals (ACNs) exhibited improved dispersion in PHBH compared with non-acetylated CNCs, and maximum thermal decomposition temperature of ACN/PHBH was 13 degrees C higher than that of neat PHBH. Compared to the neat PHBH and CNC/PHBH, 57.6% and 24.5% improvements in tensile strength, and 52.4% and 30.6% improvements in Young's modulus were obtained for the bionanocomposites. The water-vapour and the oxygen barrier properties of ACN/PHBH improved by 76.1% and 30.4% compared with CNC/PHBH samples. Simultaneous enhancements on the thermal stability, mechanical and barrier properties were mainly caused by uniform dispersion of ACNs and solid interfacial bonding between filler and matrix. This performance of the bionanocomposite will broaden the utilization of CNCs as renewable bioresources and the practical application of PHBH-based plastics as replacements for traditional petrochemical materials. Graphic abstract
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