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Chiral pesticides levels in peri-urban area near Yangtze River and their correlations with water quality and microbial communities

文献类型： 外文期刊

作者： Zhang, Wenjun 1 ; Di, Shanshan 2 ; Yan, Jin 3 ;

作者机构： 1.Hohai Univ, Coll Environm, Key Lab Integrated Regulat, Resources Dev Shallow Lakes Minist Educ, Nanjing 210098, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, State Key Lab Managing Biot & Chem Threats Qual &, key Lab Detect Pesticide Residues & Control Zhejia, Hangzhou 310021, Peoples R China

3.Suzhou Univ Sci & Technol, Sch Environm Sci & Engn, Natl & Local Joint Engn Lab Municipal Sewage Resou, Suzhou 215009, Peoples R China

关键词： Non-point source pollution; Distribution; Enantiomers; Risk assessment; Redundancy analysis

期刊名称：ENVIRONMENTAL GEOCHEMISTRY AND HEALTH （ 影响因子：4.898； 五年影响因子：4.932 ）

ISSN： 0269-4042

年卷期：

页码：

收录情况： SCI

摘要： Pesticides are considered to be the second-largest non-point source pollution in water. Our research assayed the river network of typical agricultural areas in the middle and lower Yangtze River as the study area. Pesticides residues in aquatic environment were determined by QuEChERS, combined with high-performance liquid chromatography tandem mass spectrometry, or gas chromatograph-mass spectrometer. At chiral pesticides' levels, we detected pesticides contents in water, classified and counted the types of pesticides, and analyzed their environmental risk assessment. Furthermore, potential correlations between chiral pesticides concentrations and water quality indicators were assayed. Additionally, we explored their relations with microbial communities at species levels. Enantiomers of Diclofop-methyl, Ethiprole, Difenoconazole and Epoxiconazole were enantioselectively distributed. More interestingly, due to various chiral environment of the sampling site, the enantiomers of Tebuconazole Acetochlor, Glufosinate ammonium and Bifenthrin had completely different distributions at different sites. Based on that, the chiral pesticides Diclofopmethyl, Bifenthrin, Ethiprole, Tebuconazole and Difenoconazole are enantioselective to the risk of aquatic environment. Generally, enantiomeric selectivity had high positive correlations with total nitrogen and phosphorus. Then we found that chiral fate behavior of Tebuconazole and Paichongding in water might be affected by prokaryotes. In addition, the chiral behavior of Diclofop-methyl, Propiconazole, Difenoconazole, and Tebuconazole isomers in water might be negatively affected by eukaryotes. That research helped us to comprehensively understand the impact of non-point source pollution of chiral pesticides in aquatic environment and provided basic data support for developing biological and water quality indicators for monitoring pollution in aquatic environment.

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