Tuning micro-wrinkled graphene films for stretchable conductors of controllable electrical conductivity
文献类型: 外文期刊
作者: Feng, Chunfang 1 ; Yi, Zhifeng 1 ; Dumee, Ludovic F. 1 ; She, Fenghua 1 ; Peng, Zheng 1 ; Gao, Weimin 1 ; Kong, Lingxu 1 ;
作者机构: 1.Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
2.CATAS, APPRI, Zhanjiang 524001, Peoples R China
3.North China Univ Sci & Technol, Sch Met & Energy, Tangshan 063009, Peoples R China
期刊名称:CARBON ( 影响因子:9.594; 五年影响因子:8.719 )
ISSN: 0008-6223
年卷期: 2018 年 139 卷
页码:
收录情况: SCI
摘要: Accurately controlling the electrical conductivity of wrinkled graphene or graphene oxide (GO) structures is challenging due to the complex sheet-to-sheet interactions and hierarchical interactions at the nanoscale. In this paper, wrinkled GO films with predictable electrical conductivity by precisely controlling thickness ranging from 0.69 to 1.68 mu m were fabricated with a thermal process where a GO-coated polystyrene shrink film was isotropically shrunk. Theoretical and experimental results show consistent dependence of the wrinkle wavelength on the GO film thickness. Beyond a certain thickness threshold, poorly wrinkled structures were formed as GO sheets started delaminating from the shrink films. A coarse-grain molecule model based on molecular dynamic simulation principles was developed to understand the formation of the wrinkles, and establish a relationship between GO thickness and the wrinkle wavelength generated. The electrical resistance was found to decrease when the thickness of the GO films increases. The formed composite film can maintain a stable electrical conductivity after experiencing up to 1000 stretching-release cycles under 10% strain. With controllable electrical conductivity, the reported composites can offer potential applications as a strain sensor with tuneable sensing range and high durability. (C) 2018 Elsevier Ltd. All rights reserved.
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