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Degradation of chloramphenicol by chlorine and chlorine dioxide in a pilot-scale water distribution system

文献类型： 外文期刊

作者： Li, Cong 1 ; Luo, Feng 2 ; Duan, Haojie 2 ; Dong, Feilong 1 ; Chen, Xiaoyang 3 ; Feng, Mingbao 4 ; Zhang, Zuoran 5 ; Cizm 1 ;

作者机构： 1.Univ Shanghai Sci & Technol, Sch Environm & Architecture, Shanghai 200433, Peoples R China

2.Zhejiang Univ, Coll Civil Engn & Architecture, Hangzhou 310027, Zhejiang, Peoples R China

3.Zhejiang Acad Agr Sci, Inst Environm Resource & Soil Fertilizer, Hangzhou 310021, Zhejiang, Peoples R China

4.Texas A&M Univ, Program Environm & Sustainabil, Dept Environm & Occupat Hlth, Sch Publ Hlth, College Stn, TX 77843 USA

5.Tongji Univ, Coll Environm Sci & Engn, Shanghai 200082, Peoples R China

关键词： Chloramphenicol; Chlorine; Chlorine dioxide; Water distribution system; Disinfection byproducts

期刊名称：SEPARATION AND PURIFICATION TECHNOLOGY （ 影响因子：7.312； 五年影响因子：6.656 ）

ISSN： 1383-5866

年卷期： 2019 年 211 卷

页码：

收录情况： SCI

摘要： This paper presents the degradation of chloramphenicol (CAP) by chlorine and chlorine dioxide (ClO2) in tap water in a pilot-scale water distribution system (WDS) containing loops of three different pipe materials (stainless steel, ductile iron, and polyethylene). Greater degradation of CAP was seen with chlorine than with chlorine dioxide. After 180 min in the ductile iron loop of the WDS, the percent degradation of CAP by 2.0 mg/L of chlorine or ClO2 was 76% and 52%, respectively. The degradation of CAP by chlorine in the WDS was investigated under various conditions, including chlorine concentrations of 1.0-4.0 mg/L, and varying pipe materials, flow velocity, and temperature. Degradation of CAP under different conditions could be fitted by first order kinetics, and the determined first-order rate constants (k, min(-1)) increased with an increase in chlorine concentration, flow velocity, and temperature. The degradation of CAP in different pipes followed the order stainless steel loop > ductile iron loop > polyethylene loop. Identified oxidized products of the chlorination of CAP were in agreement with proposed reaction pathways, which were also theoretically confirmed by quantum chemical calculations. Formation of three disinfection byproducts (chloroform, bromodichloromethane, and dibromochloromethane) was observed, with increases of 71, 0.76, and 0.39 mu g/L, respectively, after 160 min.

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