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Analysis of the steady-state concentrations of reactive species and their role in contaminant degradation by the iron-biochar/persulfate advanced oxidation process: Comparison of probe compound and quenching agent methods

文献类型： 外文期刊

作者： Meng, Xukun 1 ; Peng, Guilong 1 ; Yan, Yuting 1 ; Wang, Xiao 1 ; Zhu, Jiangwei 2 ; Belver, Carolina 3 ; Gong, Wenwen 4 ; Blaney, Lee 5 ;

作者机构： 1.Southwest Univ, Coll Sericulture Text & Biomass Sci, State Key Lab Resource Insects, Chongqing 400715, Peoples R China

2.Nanjing Forestry Univ, Coinnovat Ctr Sustainable Forestry Southern China, Nanjing 210037, Peoples R China

3.Univ Autonoma Madrid, Chem Engn Dept, Campus Cantoblanco, E-28049 Madrid, Spain

4.Beijing Acad Agr & Forestry Sci, Inst Qual Stand & Testing Technol, Beijing 100097, Peoples R China

5.Univ Maryland Baltimore Cty, Dept Chem Biochem & Environm Engn, Baltimore, MD 21250 USA

6.Southwest Univ, Yibin Acad, Yibin, Peoples R China

关键词： Reactive species; Persulfate; Steady-state concentration; Iron-biochar; Advanced oxidation processes

期刊名称：SEPARATION AND PURIFICATION TECHNOLOGY （ 影响因子：8.1； 五年影响因子：7.6 ）

ISSN： 1383-5866

年卷期： 2025 年 354 卷

页码：

收录情况： SCI

摘要： Reactive species, including hydroxyl radicals (center dot OH), sulfate radicals (SO4 center dot- ), singlet oxygen (1O2), superoxide radicals (O2 center dot- ), and Fe(IV), are generated by the iron-biochar activated persulfate (Fe-BC/PS) process. These reactive species can be leveraged for treatment of micropollutants, such as the sulfamethoxazole antibiotic. In this study, the steady-state concentrations and contributions of center dot OH, SO4 center dot-, 1O2, O2 center dot- , and Fe(IV) to sulfamethoxazole degradation were calculated for different operating conditions in the iron-biochar/persulfate (Fe-BC/PS advanced oxidation process. Electron paramagnetic resonance was employed to confirm the production of each reactive species. The nitrobenzene, benzoic acid, furfuryl alcohol, p-chlorobenzoic acid or p-benzoquinone, and phenyl methyl sulfoxide probe compounds were added to experimental solutions in isolation, as mixtures, and at different concentrations to calculate the steady-state concentrations of center dot OH, SO4 center dot-, 1O2, O2 center dot-, and Fe(IV) and determine their contributions to sulfamethoxazole degradation at variable pH conditions. The results not only informed the primary mechanisms of sulfamethoxazole degradation by the Fe-BC/PS system, but also highlighted best practices for the use of probe compounds and quenching agents in persulfate-based advanced oxidation processes. In particular, the initial concentration of the probe compounds should be as low as possible to avoid impacts on target contaminant degradation and misinterpretation of the role of each reactive species. Furthermore, quenching-based approaches to determination of the key reactive species were less consistent than evaluation by probe compounds. The overall outcomes of this work inform sulfamethoxazole treatment by the Fe-BC/ PS system and emphasize the need for internal validation of kinetics results using a multi-pronged approach.

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