Enabling 10C-rate fast charging in LiFePO4 based lithium-ion battery by balancing the electronic and ionic conductivity paths in cathode
文献类型： 外文期刊
作者： Xia, Kang 1 ; Yao, Zhengyin 1 ; Zhao, Pengfei 2 ; Liu, Zhen 4 ; Zhao, Shuo 1 ; Peng, Zheng 2 ; Zhang, Peng 1 ;
作者机构： 1.Sun Yat Sen Univ, Inst Green Chem & Mol Engn, Sch Mat Sci & Engn, Key Lab Polymer Composite & Funct Mat,Minist Educ, Guangzhou 510275, Peoples R China
2.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China
3.Chinese Acad Trop Agr Sci, Sanya Res Inst, Sanya 572024, Peoples R China
4.South China Univ Technol, Med Devices Res & Testing Ctr, Guangzhou 510006, Peoples R China
关键词： Lithium-ion battery; High-rate charging; Conductive network; Elastomer; Cathode
期刊名称：CHEMICAL ENGINEERING JOURNAL （ 影响因子：13.2； 五年影响因子：13.5 ）
ISSN： 1385-8947
年卷期： 2025 年 506 卷
页码：
收录情况： SCI
摘要： The challenge of high-rate charging remains a critical barrier for the widespread adoption of lithium-ion batteries (LIBs). In this study, we address this issue by employing a novel binder, poly(methyl methacrylate)-graftednatural rubber (PMMA-g-NR), for lithium iron phosphate (LFP) cathodes. This amphiphilic binder not only improves ionic and electronic conductivities but also prevents macro-phase segregation of LFP and conductive carbon, ensuring uniform distribution. The unique microphase morphology, governed by the "like dissolves like" principle, enriches conductive carbon in NR domains and LFP particles in PMMA domains, enhancing the synergy between the ionic and electronic transport pathways. The resulting LFP||Li cells exhibit exceptional rate performance, maintaining 64% capacity retention after 1200 cycles at 10C. Furthermore, the binder's excellent elasticity preserves electrode integrity during repeated cycling. This work highlights the critical role of binder design in advancing high-rate charging capabilities, offering a scalable solution to improve the fast-charging performance and longevity of LIBs.
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