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Environmental Behavior of the Chiral Organophosphorus Insecticide Acephate and Its Chiral Metabolite Methamidophos: Enantioselective Transformation and Degradation in Soils

文献类型： 外文期刊

作者： Wang, Xiangyun 1 ; Li, Zhen 1 ; Zhang, Hu 1 ; Xu, Junfeng 1 ; Qi, Peipei 1 ; Xu, Hao 2 ; Wang, Qiang; Wang, Xinquan;

作者机构： 1.Zhejiang Acad Agr Sci, Inst Qual & Stand Agr Prod, State Key Lab Breeding Base Zhejiang Sustainable, Agr Minist Key Lab Pesticide Residue Detect,Zheji, Hangzhou 310021, Zhejiang, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Qual & Stand Agr

期刊名称：ENVIRONMENTAL SCIENCE & TECHNOLOGY （ 影响因子：9.028； 五年影响因子：9.922 ）

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收录情况： SCI

摘要： Acephate is a widely used organophosphorus insecticide globally, although there are some concerns about its usage with regard to acute consumer exposure and side-effects on nontarget organisms. These concerns are always attributed to the acephate metabolite methamidophos. In the many reports about the environmental behavior of acephate and its metabolite, none pay any attention to the chirality of them. In this study, the enantiomeric transformation and degradation of acephate was investigated in three soils under laboratory conditions using enantioselective GC-MS/MS. Racemic and enantiopure compounds were incubated in separate experiments. The degradation of racemates was shown to be enantioselective in unsterilized soils but not in the sterilized soils, thus confirming the enantioselectivity was microbially based. The priority of enantiomer degradation and transformation varied among soils and racemates. R-(+)-methamidophos was enriched in the Zhengzhou soil, but degraded faster in the Changchun and Nanchang soils than its antipode. For acephate, the Nanchang soil enriched R-(+)-acephate, and S-(—)-acephate accumulated in the other two soils. Acephate and methamidophos were both configurationally stable in soil, showing no interconversion of R-(+)- to S-(—)-enantiomers, or vice versa. The conversion of acephate to methamidophos proceeded with retention of configuration. Generally, the degradation followed approximate first-order kinetics, but showed significant lag phases.

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