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Decomposition and mineralization of sulfaquinoxaline sodium during UV/H2O2 oxidation processes

文献类型： 外文期刊

作者： Liao, Qi-Nan 1 ; Ji, Feng 2 ; Li, Jun-Chao 1 ; Zhan, Xinmin 3 ; Hu, Zhen-Hu 1 ;

作者机构： 1.Hefei Univ Technol, Sch Civil Engn, Hefei 230009, Peoples R China

2.Beijing Acad Agr & Forestry Sci, Inst Anim Husb & Vet Med, Beijing 100097, Peoples R China

3.Natl Univ Ireland, Coll Engn & Informat, Galway, Ireland

4.Hefei Univ Technol, Inst Water Treatment & Wastes Reutilizat, Sch Civil Engn, Hefei 230009, Peoples R China

关键词： Advanced oxidation processes;Decomposition;Mineralization;Pathway;Sulfaquinoxaline sodium;UV/H2O2 oxidation

期刊名称：CHEMICAL ENGINEERING JOURNAL （ 影响因子：13.273； 五年影响因子：11.529 ）

ISSN：

年卷期：

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收录情况： SCI

摘要： Sulfaquinoxaline sodium (N/1-quinoxalin-2-ylsulphanilamide sodium, SQ-Na) has been widely used to prevent coccidiosis in poultry, swine, and sheep. The quinoxaline group within SQ-Na exhibits mutagenic and carcinogenic properties. The removal of residual SQ-Na from wastewater has not been reported before. In this study, the decomposition of SQ-Na in aqueous solutions in UV/H2O2 oxidation process was investigated. The results show that SQ-Na was completely decomposed during UV/H2O2 oxidation process, and the process fitted a fluence-based pseudo-first-order kinetics model when the initial H2O2 concentration varied from 0 to 160 mg/L with rate constant of k(obs) = 0.802 x [H2O2] + 0.206 x 10(-3) (R-2 = 0.990). The decomposition of SQ-Na via UV/H2O2 process was favorable under acidic and neutral conditions but was inhibited under strong alkaline conditions (pH >= 11). The presence of bicarbonate, chloride and nitrate ions were shown to have slight inhibition on the decomposition, but humic acids significantly decreased the decomposition rate. As compared with in deionized water, the decomposition rate of SQ-Na in surface water and wastewater treatment plant (WWTP) effluent was significantly decreased at 80 mg/L of H2O2, but the decrease was mitigated with more H2O2 addition. The decomposition products of SQ-Na were identified using ion chromatography and liquid chromatography with an ion trap and time-of-flight mass spectrometry (LCMS-IT-TOF). Based on these decomposition products, the possible decomposition pathways of SQ-Na in the UV/H2O2 oxidation process were proposed. (C) 2015 Elsevier B.V. All rights reserved.

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