Comparison of Pb(II) Immobilized by Bone Char Meal and Phosphate Rock: Characterization and Kinetic Study
文献类型: 外文期刊
作者: Chen, Shibao 1 ; Ma, Yibing 1 ; Chen, Li 4 ; Wang, Liqun 1 ; Guo, Haitao 1 ;
作者机构: 1.Chinese Acad Agr Sci, Minist Agr, Key Lab Plant Nutr & Nutrient Cycling, Beijing 100081, Peoples R China
2.Chinese Acad Agr Sci, Inst Agr Resources & Reg Planning, Beijing 100081, Peoples R China
3.Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, Nanjing 210008, Peoples R China
4.Beijing Acad Agr & Forestry Sci, Inst Plant Protect & Environm Protect, Beijing 100097, Peoples R China
期刊名称:ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY ( 影响因子:2.804; 五年影响因子:3.399 )
ISSN: 0090-4341
年卷期: 2010 年 58 卷 1 期
页码:
收录情况: SCI
摘要: Adsorption isotherms and kinetics of aqueous Pb(II) by bone char meal (BM) and phosphate rock (PR) were investigated using batch experiments. Pb removal was characterized and effects of pH and reaction time on Pb removal efficiency by BM/PR were also investigated. Results indicated that Pb removal efficiency by BM and PR is mainly controlled by dissolution of phosphatic components associated with apatite, followed by subsequent precipitation of geochemically stable pyromorphite [Pb(10) (PO(4))(6)(OH,Cl)(2)]. Sorption kinetics results indicated that Pb sorption onto BM or PR was generally biphasic, with initially fast reactions followed by slow and continuous reactions. Pb removal efficiency by BM and PR increased with increasing pH except at a pH higher than 6.15. Sorption isotherms showed that BM has a much higher Pb removal rate than PR in solution; the greater capability of BM than of PR to remove aqueous Pb indicates its potential as another promising way to remediate Pb-contaminated media.
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