Unraveling how Fe-Mn modified biochar mitigates sulfamonomethoxine in soil water: The activated biodegradation and hydroxyl radicals formation
文献类型： 外文期刊
作者： Wang, Yuying 1 ; Lyu, Haohao 1 ; Du, Yuqian 1 ; Cheng, Qilu 1 ; Liu, Yuxue 1 ; Ma, Junwei 1 ; Yang, Shengmao 1 ; Lin, Hui 1 ;
作者机构： 1.Inst Environm Resource Soil & Fertilizers, Zhejiang Acad Agr Sci, State Key Lab Managing Biot & Chem Threats Qual &, Hangzhou 310021, Peoples R China
2.Engn Res Ctr Biochar Zhejiang Prov, Hangzhou 310021, Peoples R China
关键词： Biochar; Soil water; Antibiotic; Degradation; Free radicals
期刊名称：JOURNAL OF HAZARDOUS MATERIALS （ 2023影响因子：12.2； 五年影响因子：11.9 ）
ISSN： 0304-3894
年卷期： 2024 年 465 卷
收录情况： SCI
摘要： This study indicated that the application of a novel Fe-Mn modified rice straw biochar (Fe/Mn-RS) as soil amendment facilitated the removal of sulfamonomethoxine (SMM) in soil water microcosms, primarily via activating degradation mechanism rather than adsorption. The similar enhancement on SMM removal did not occur using rice straw biochar (RS). Comparison of Fe/Mn-RS with RS showed that Fe/Mn-RS gains new physicchemical properties such as abundant oxygenated C -centered persistent free radicals (PFRs). In the Fe/Mn-RS microcosms, the degradation contributed 79.5-83.8% of the total SMM removal, which was 1.28-1.70 times higher than that in the RS microcosms. Incubation experiments using sterilized and non -sterilized microcosms further revealed that Fe/Mn-RS triggered both the biodegradation and abiotic degradation of SMM. For abiotic degradation of SMM, the abundant center dot OH generation, induced by Fe/Mn-RS, was demonstrated to be the major contributor, according to EPR spectroscopy and free radical quenching experiments. Fenton -like bio-reaction occurred in this process where Fe (III), Mn (III) and Mn (IV) gained electrons, resulting in oxidative hydroxylation of SMM. This work provides new insights into the impacts of biochar on the fates of antibiotics in soil water and a potential solution for preventing antibiotic residues in agricultural soil becoming a non -point source pollutant.
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