Rational Fabrication of Polyhedral Oligomeric Silsesquioxane-Based Porous Organic Polymers Sustainably Used for Selective CO2 Adsorption
文献类型： 外文期刊
作者： Li, Tiantian 1 ; Kang, Guodong 2 ; Liu, Mengqi 2 ; Sun, Congcong 2 ; Li, Jie 3 ; Meng, Yang 4 ; Xue, Dingming 2 ;
作者机构： 1.Xuzhou Coll Ind Technol, Sch Chem Engn & Technol, Xuzhou 221140, Jiangsu, Peoples R China
2.Minist Ecol & Environm, Nanjing Inst Environm Sci, 8 Jiangwangmiao St, Nanjing 210042, Peoples R China
3.Fujian Acad Agr Sci, Inst Food Sci & Technol, Fuzhou 350003, Peoples R China
4.CAS Haixi Ind Technol Innovat Ctr Beilun, Ningbo Key Lab Urban Environm Pollut & Control, Ningbo 315830, Peoples R China
关键词： CO2 capture; POSS; adsorption; selectivity; porous polymers
期刊名称：PROCESSES （ 影响因子：2.8； 五年影响因子：3.1 ）
ISSN：
年卷期： 2024 年 12 卷 11 期
页码：
收录情况： SCI
摘要：
Different types of porous materials have been developed for the efficient separation of CO2 from mixtures of gases. Nevertheless, the most porous materials cannot be used for extensive industrial applications due to their non-negligible disadvantages, such as complex synthesis routes, expensive monomers, and/or costly catalysts. Therefore, a strategy for fabricating a series of polyhedral oligomeric silsesquioxane (POSS)-based porous organic polymer materials (PBPOPs) was developed through the simple condensation reaction of octaphenylsilsesquioxane and different bromine-containing monomers. It was found that PBPOP-2 exhibits the best CO2 adsorption amount of 41 cm(3)
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